A Al-Kahwaji | PubMed Health

PubMed2001

Shear-induced first-order sponge-to-lamellar transition in a lyotropic surfactant system.

We report a shear-induced sponge (L3) to lamellar (L(alpha)) transition in a surfactant system. Under a constant shear rate, after a delay time t(n) we observe random nucleation and subsequent growth of the L(alpha) phase, demonstrating that the shear-induced transition is first order. A simple argument for the energy of a two-dimensional nucleus accounts for the observed delay and its shear-rate dependence.

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PubMed2000

Coupling between flow and structure for a lamellar surfactant phase

The flow-structure relation of lamellar phases is studied using rheometry and cross-polarized microscopy under flow. The equilibrium phases show different defects. Low salinities lead to very viscous, "onion" phases, whereas at high salinity, a low viscosity plane lamellar phase is found. Under shear, the latter shows a sudden transition to a viscoelastic gel, with a texture and viscosity very similar to that of the onions. Gelation occurs after a certain delay time, increasing rapidly with salinity, by the nucleation of onions. This allows one to relate the delay time to the defect energy.

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