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A Buhot

Publications and source records attributed to A Buhot.

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Crossover from fragile to strong glassy behavior in kinetically constrained systems.

We show the existence of fragile-to-strong transitions in kinetically constrained systems by studying the equilibrium and out-of-equilibrium dynamics of a generic constrained Ising spin chain that interpolates between the symmetric and fully asymmetric cases. We find that for large but finite asymmetry the model displays a crossover from fragile to strong glassy behavior at finite temperature, which is controlled by the asymmetry parameter. The relaxation in the fragile region presents stretched exponential behavior, with a temperature dependent stretching exponent that is predicted. Our results are confirmed by numerical simulations.

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Extension of rod-coil multiblock copolymers and the effect of the helix-coil transition

The extension elasticity of rod-coil mutliblock copolymers is analyzed for two experimentally accessible situations. In the quenched case, when the architecture is fixed by the synthesis, the force law is distinguished by a sharp change in the slope. In the annealed case, where interconversion between rod and coil states is possible, the resulting force law is sigmoid with a pronounced plateau. This last case is realized, for example, when homopolypeptides capable of undergoing a helix-coil transition are extended from a coil state.

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