Biomedical subjects

A J Feitz

Publications and source records attributed to A J Feitz.

4 recordsLinked to original sources

PubMed2005

Steroid estrogens in ocean sediments.

This paper gives results from a study measuring the abundance of steroid hormones in ocean sediments in the proximity of a deep ocean sewage outfall. The outfall is discharge point for an enhanced primary sewage treatment plant and sediment samples were taken adjacent and 7 km from the outfall. All samples contained steroid estrogens at nanogram per gram levels with higher concentrations at the 7 km sampling site. The concentration of estrone ranged from (0.16-1.17 ng/g), 17beta-estradiol (0.22-2.48 ng/g) and the synthetic 17alpha-ethinylestradiol (<0.05-0.5 ng/g). The values detected correspond with estimates based on the proportion of estrogens sorbed to particles in the effluent and the expected proportion of particles originating from sewage in the ocean sediments. The results suggest that estrogens associated with the particulate fraction aggregate on contact with high ionic strength seawater and settle to the seafloor after discharge through deep ocean outfalls.

Adsorption↗

PubMed2005

Steroid estrogens in primary and tertiary wastewater treatment plants.

The concentrations of two natural estrogens (estrone (E1) and Estradiol (E2)) and one synthetic progestin (Ethinylestradiol (EE2)) were measured for different unit operations in an advanced sewage treatment plant and in a large coastal enhanced primary sewage treatment plant. The average influent concentration to both plants was similar: 55 and 53 ng/L for E1 and 22 and 12 ng/L for E2 for the advanced and enhanced primary STPs, respectively. The activated sludge process at the advanced STP removed up to 85% and 96% of E1 and E2, respectively. The enhanced primary sewage treatment plant was mostly ineffective at removing the steroids with only 14% of E1 and 5% of E2 being removed during the treatment process. EE2 was not been detected during the study period in the influent or effluent of either STP. The difference in the observed removal between the two plants is primarily linked to plant performance but the extent to which removal of steroid estrogens is due to bacterial metabolism (i.e. the advanced STP) rather than adsorption to the bacterial biomass remains unclear. The poor removal observed for the coastal enhanced primary STP may have implications for the receiving environment in terms of a greater potential for abnormal reproductive systems in marine animals, particularly if discharges are into large bays or harbours where flushing is limited.

Bacteria↗

PubMed2001

Size and structure effects on centrifugal dewatering of digested sewage sludge.

The application of light scattering over small angles for the determination of digested sludge floc size and structure and its relationship with dewaterability is investigated. It appears that improved dewatering corresponds with lower floc fractal dimension (a more open structure) and a smaller proportion of fine particles. The initial increase in fractal dimension with increasing polymer dose for the digested sludge is most likely due to more efficient aggregation of the finer particles and the resulting formation of denser particle aggregates. A large colloidal fractal of the digested sludge (< 10 microm) appears to be less negative than the bulk digested sludge. This suggests that the fine particles will react differently and possibly less aggressively to the cationic polymer than the larger and more negative particles. The higher negative charge associated with the larger particles might be related to greater levels of highly negatively charged extracellular polysaccharides (EPS) adsorbed to the flocs or could result from the association of FeS with the finer fraction. The appearance of much greater levels of fine particles after digestion suggests that the flocs have undergone disintegration. Whether this is due to reduced biological efficiency within the digestor or iron reduction under the anaerobic conditions is not known for certain, although no indication of prolonged stress in the digesters could be found from plant performance data.

Centrifugation↗

PubMed2001

Effect of Fe(III)-ligand properties on effectiveness of modified photo-Fenton processes.

This paper examines a modified photo-Fenton (UV/Fe oxalate/H2O2) process. The degradation of oxalate in this system in the absence of Reactive Red 235 was studied using both experimentation and kinetic modelling. The degradation of Reactive Red 235 in this system was also studied. Light intensity and solution pH had large effects on the degradation of both oxalate and Reactive Red 235, with the effect of pH not due simply to speciation changes. The most important properties of the oxalate ligand in the UV/Fe oxalate/H2O2 process are that it forms Fe(III)-oxalato complexes that are easily photolysed and also is relatively unreactive with OH. radicals.

Coloring Agents↗