Controlling the growth of polymer trees: concepts and perspectives for hyperbranched polymers.
This article summarizes basic principles and recent progress in the field of cascade-branched polymers. Methods for the preparation of macromolecules with hyperbranched structures are presented and compared concerning the extent of control over molecular weights and polydispersity. Step-growth and recently developed chain-growth strategies as well as enzyme and transition metal catalyzed polymerizations are discussed with respect to mechanism and future potential.