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Akihiko Nakatsuka

Publications and source records attributed to Akihiko Nakatsuka.

2 recordsLinked to original sources

Oxygen-deficient strontium cobaltate, SrCoO2.64.

Single crystals of strontium cobaltate, SrCoO(3-x), have been grown by the floating-zone method in an oxygen flow. The compound crystallizes with the cubic perovskite structure, with Pm-3m symmetry, as determined by X-ray diffraction. Refinement of the O-atom site occupancy yields the chemical composition SrCoO(2.64) [x = 0.36 (3)]. The anisotropic displacement ellipsoids of the O atoms suggest that their positional disorder occurs in a direction perpendicular to that of the Co-O bonds.

Journal Article↗

Vanadate garnet, Ca2NaMg2V3O12.

The vanadate garnet Ca(2)NaMg(2)V(3)O(12) (dicalcium sodium dimagnesium trivanadium dodecaoxide), synthesized by a floating zone method, has a notable structural feature in that the dodecahedral-dodecahedral shared edge length is longer than the unshared dodecahedral edge length. It is also noteworthy that the octahedral-dodecahedral shared edge length is as long as the unshared octahedral edge length. These unusual structural features are closely related to the weak repulsions between dodecahedral cations and between dodecahedral and octahedral cations.

Journal Article↗