Triferrocenylphosphine oxide monohydrate.
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Biomedical subjects
Alfred Muller
Publications and source records attributed to Alfred Muller.
cis-Diphenylbis(1,3,5-triaza-7-phosphaadamantane-kappaP)platinum(II).
The structure of the title compound, [Pt(C(6)H(5))(2)(C(6)H(12)N(3)P)(2)] or [Pt(Ph)(2)(PTA)(2)] (where Ph is phenyl and PTA is 1,3,5-triaza-7-phosphaadamantane), is discussed. Selected geometric parameters are: Pt-P = 2.2888 (16) and 2.2944 (17) A, Pt-C = 2.052 (5) and 2.064 (6) A, C-Pt-C = 84.6 (2) degrees and P-Pt-P = 99.28 (6) degrees. The effective cone angle for the PTA ligands was calculated as 113 degrees.
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[2-(Anilinomethyl)phenyl]diphenylphosphine and [2-[(N-methylanilino)methyl]phenyl]diphenylphosphine.
The title compounds, Ph(2)PCH(2)N(H)Ph or C(25)H(22)NP and Ph(2)PCH(2)N(CH(3))Ph or C(26)H(24)NP, respectively, are isomorphous, with calculated theoretical Tolman angles of 174 and 182 degrees.
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