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Anthony K Cheetham

Publications and source records attributed to Anthony K Cheetham.

21 records · Page 2Linked to original sources

GaFPO(3)(C(6)H(5)): a new fluorinated gallium phenylphosphonate with a layered network.

Crystals of gallium fluorophenylphosphonate were synthesized hydrothermally at 453 K under autogenous pressure. The solid crystallizes in the monoclinic system and its structure is built up by the connection of zigzag chains of edge-sharing GaO(4)F(2) octahedra to phenylphosphonate groups. This results in the formation of a layered structure, in which the phenyl groups point upward and downward from the inorganic sheet. The Ga atoms occupy the special positions 4a (inversion center) and 4e (twofold axis).

Journal Article↗

Direct observation of host-guest hydrogen bonding in the zeolite NaY/chloroform system by neutron scattering.

The differential H pair distribution function obtained from neutron scattering contrast measurements on hydrogenous and deuterated chloroform adsorbed into zeolite NaY (two molecules per supercage) reveals direct evidence for hydrogen bonding between hydrogen atoms on the sorbate molecule and oxygen atoms of the zeolite framework. A vector between the hydrogen and framework Si/Al atoms is also observed. The results confirm the conclusions drawn from previous vibrational spectroscopy and computer modeling studies.

Journal Article↗