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B K McCoy

Publications and source records attributed to B K McCoy.

5 recordsLinked to original sources
PubMed2006

Smectic-Calpha*-smectic-C* phase transition and critical point in binary mixtures.

We have investigated the smectic-Calpha*-smectic-C* (SmCalpha*-SmC*) transition in a series of binary mixtures with resonant x-ray diffraction, differential optical reflectivity, and heat capacity measurements. Results show that the phases are separated by a first-order transition that ends at a critical point. We report the observation of such a critical point. We have proposed the appropriate order parameter and obtained values of two critical exponents associated with this transition. The values of the critical exponents suggest that long-range interactions are present in the SmCalpha*-SmC* critical region.

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PubMed2006

Optical studies on the surface-induced tilted layers in freestanding films of two no-layer-shrinkage liquid crystal compounds.

Null transmission ellipsometry has been employed to study the molecular arrangements in freestanding films of two no-layer-shrinkage liquid crystal homologous compounds above the bulk smectic A-smectic C* (Sm C*) transition temperature. An unusual nonplanar-parallel or nonplanar-antiparallel-parallel transition has been observed in both compounds under a proper electric field. With the addition of one CH2 group, while the SmC* phase is more stable thermally, the magnitude of the critical field needed to induce a parallel-antiparallel transition decreases dramatically.

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PubMed2006

Investigations of nanoscale helical pitch in smectic-C*alpha and smectic-C* phases of a chiral smectic liquid crystal using differential optical reflectivity measurements.

Differential optical reflectivity (DOR) was used to study the temperature dependence of the short helical pitch in freestanding films of a liquid crystal compound. The experimentally measured DOR signal was fitted using Berreman's 4 x 4 matrix method to get the pitch value in the smectic-C*alpha (sMC*alpha) phase. The results show continuous evolution of the pitch between the smectic-C*alpha and sMC*alpha phases. In sMC*alpha, the pitch decreases as temperature increases and is found to level off at 16+/-1 smectic layers at the sMC*alpha to smectic-A* transition.

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PubMed2006

Surface-induced multiple reentrant transitions.

We have studied tilted surface layers in the bulk SmA temperature window of one liquid crystal using null transmission ellipsometry. Five distinct nonplanar surface structures were observed. We present analyses of the tilt and azimuthal profiles of the structures and examine the transitions between the structures. The transitions are identified as a double reentrant synclinic-anticlinic-synclinic-anticlinic transition. Meanwhile, the transitions also display reentrant ferroelectric-antiferroelectric-ferroelectric behavior.

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PubMed2006

Optical and resonant X-ray diffraction studies confirm a SmC*FI2-SmC* liquid crystal phase sequence reversal.

Employing both null transmission ellipsometry and resonant x-ray diffraction, we confirmed the SmC*FI2-SmC* phase sequence reversal in one liquid crystal compound and specially prepared binary mixtures. This phase sequence reversal was predicted by two recent theoretical advances. Moreover, the temperature range for the SmC*FI2 phase increases significantly in the mixture suggesting that such a phase sequence may exist in other compounds.

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