Biomedical subjects

B M Law

Publications and source records attributed to B M Law.

6 recordsLinked to original sources

PubMed2001

Casimir force in a critical film formed from an electrolytic solution.

We have studied the thickness of vapor adsorbed films of the critical binary liquid mixture acetic acid plus nonane adsorbed onto a silicon wafer substrate as a function of temperature near the critical temperature. This critical film possesses opposite boundary conditions (+-) at its two surfaces and, due to the dissociation of acetic acid, both the electrostatic force and the dispersion force affect the adsorbed film thickness. On approaching the critical temperature T(c), an increase in the film thickness L is observed, implying that the sign of the universal Casimir amplitude Delta(+-) is positive, consistent with theoretical predictions. However, we find quantitative discrepancies in the value of Delta(+-) and the form of the critical Casimir pressure scaling function vartheta(+-) compared with previous experimental results. We attribute these discrepancies to the complex nature of the critical system studied in this experiment.

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PubMed2001

Critical adsorption in the weak surface field limit.

We study critical adsorption in the small surface field (h(1)) limit using a homologous series of critical liquid mixtures. The experiment data, in the one-phase regime, is accurately described by a universal surface scaling function G+(z/xi(+),z/l(h)) at distance z from the interface with correlation length xi(+) and surface field length l(h) approximately absolute value of (h(1))(-nu/Delta(1)), where h(1) approximately Deltasigma, the surface energy difference between the two components.

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PubMed2001

Line tension approaching a first-order wetting transition: experimental results from contact angle measurements.

The line tension values of n-octane and 1-octene on a hexadecyltrichlorosilane coated silicon wafer, are determined by contact angle measurements at temperatures near a first-order wetting transition T(w). It is shown experimentally that the line tension changes sign as the temperature increases toward T(w) in agreement with a number of theoretical predictions. A simple phenomenological model possessing a repulsive barrier at l(0)=5.1+/-0.2 nm and a scale factor of B=78+/-6 provides a quantitative description of the experiments.

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PubMed2000

Dipole orientational order at the critical interface.

We present experimental evidence that dipoles exhibit orientational order at the critical interface of mixtures of polar plus nonpolar liquids using the technique of ellipsometry. In this technique the ellipticity rho; at the critical interface for all nonpolar or weakly polar fluids or fluid mixtures diverges as t(beta-nu) where t=(Tc-T)/Tc is the reduced temperature relative to the critical temperature Tc and beta=0.328, nu=0.632 are critical exponents. For polar fluids, however, the dipole-image dipole interaction at the interface can cause long-range orientational order resulting in deviations from this power-law divergence. Theoretical results predict that the surface orientational order parameter alpha2(z) approximately m(*4)[d2v(z)/dz2], where m(*) is the reduced dipole moment and v(z) is the local composition at position z within the interface. We find quantitative agreement with these predictions for two different critical binary liquid mixtures composed of a highly polar plus nonpolar component.

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PubMed1999

Universal surface scaling function for critical adsorption.

We present an accurate determination of the one- and two-phase universal surface scaling function which describes critical adsorption at noncritical interfaces of critical binary liquid mixtures in the strong surface field limit. The 95% confidence levels for this function are also determined. This function quantitatively describes ellipsometric critical adsorption data for three upper critical and one lower critical binary liquid mixtures.

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PubMed1999

Spreading dynamics of terraced droplets.

The liquid crystal (-)7S5 spreads as a two-terraced droplet on an oxide covered (100) Si wafer. The thickness of the upper and lower terraces are respectively approximately 200 and approximately 40 A. This is the simplest system for which the de Gennes and Cazabat (dGC) terraced spreading model [C. R. Acad. Sci. II 310, 1601 (1990)] is applicable. We find that soon after the upper terrace acquires a flat top a hole develops in the center of this terrace. The hole propagates down to the depth of the first terrace. In this contribution we demonstrate that the dGC model is unstable to the formation of a hole in the center of the upper terrace for a two-terraced droplet. Our extended dGC model, which includes a hole in the upper terrace, provides a reasonable description of the average spreading dynamics for this system. However, this model has difficulties quantitatively accounting for all of the features exhibited by the dynamics, perhaps because experimentally the inner and outer borders of the upper terrace become irregular with time. These irregularities in the borders have not been included within the model.

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