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Biomedical subjects

C H Lloyd

Publications and source records attributed to C H Lloyd.

At least 55 records · Page 3Linked to original sources

Thermal diffusivity of composite restorative materials.

The substantial increases in the filler volume fraction of the current generation of composite resins, and the incorporation of radiopacifying heavy elements in many of these fillers, constitute significant changes which may affect thermal transport properties. Thermal diffusivity has been determined for 21 of these composite materials recommended for anterior and posterior applications. For radiopaque hybrid and for microfine composites, there was, however, only a gradual trend to increased thermal diffusivity with increasing volume fraction of inorganic filler. The diffusivity values were not greatly in excess of the level observed for dentin. Nevertheless, a small group of materials, incorporating substantial amounts of quartz or silicon nitride filler particles, exhibited high rates of thermal diffusion, up to three times the level exhibited by dentin.

Composite Resins↗

The fracture toughness of repaired composite.

The fracture toughness (K'IC) at the interface formed between a composite substrate and more recently placed composite has been measured to determine the strength of the repair. The substrate material was 24 h old at the time of the repair and the fracture toughness of the repair was measured 24 h later. Five composite products were selected for repair by using either that particular product or one of the others. Repairs were made to clean fractured surfaces, and these after contamination with artificial saliva. The fracture toughness factor of any repair was significantly less than that for the respective control. The effect of surface contamination proved highly significant and reduced the fracture toughness. An interaction existed between adherend (substrate) and adhesive (addition) materials. Compatibility between these for matrix and initiation chemistries did not appear to be significant.

Acrylic Resins↗

The fracture toughness (KIC) of amalgam.

The fracture toughness (KIC) has been measured (at 1 week) for a selection of sixteen amalgam products. This included low copper (i.e. Cu less than 6%) and high copper (both single component and admixed) products in milled and spherical powder forms. The results have shown that the fracture toughness decreases progressively as the copper content increases. The admixed high copper products possess superior fracture toughness to those containing a single component powder. These results have been attributed to differences in the microstructures produced by changes in composition and form in which the copper addition is made.

Copper↗

A differential thermal analysis (DTA) for the heats of reaction and temperature rises produced during the setting of tooth coloured restorative materials.

Differential thermal analysis (DTA) has been used to obtain the temperature rises produced during the setting of a range of tooth coloured restorative materials, which included silicates, glass ionomers and composites. These have been compared on the basis of the temperature rise per unit volume of material. Calibration of the areas under the reaction peaks (produced during this isothermal operation) to obtain heats of reaction is discussed and a method described. As for the temperature rises, values are given per unit volume of material. The results are compared with those reported in other studies from which DTA is seen to be a technique suited to the determination of these parameters and which might be considered for use a standard method.

Chemical Phenomena↗

The fracture toughness of tooth coloured restorative materials.

A fracture mechanics approach has been used to quantify the failure of tooth coloured restorative materials which are subjected to tensile forces. The materials examined included silicates, glass ionomers, composites (both chemically and photo-initiated) and bonding resins for composites. The parameter chosen was the plane strain critical stress intensification factor, KIC. Silicate and glass ionomer are both brittle and have values for KIC inferior to those of composites. Composites have fracture toughnesses in a range from marginally higher than that of the bonding resin to almost three times that figure. The reason for this is discussed in terms of the dispersion toughening theories.

Chemical Phenomena↗

The heats of reaction and temperature rises associated with the setting of bonding resins.

DTA has been used to obtain the heats of reaction and temperature rises occurring during the setting of bonding resins. Four products have been examined. There was little difference between these. Setting reactions were highly exothermic and produced substantial temperature rises. Both factors are linearly related to resin volume, thus it is fortunate that this material is employed in small volumes, but problems may arise from spillage or the careless application of excessive quantities.

Bisphenol A-Glycidyl Methacrylate↗