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C Jungen

Publications and source records attributed to C Jungen.

10 recordsLinked to original sources

Quantum beats and Kepler motion in fast competing photoionization and photodissociation processes

Electronic and nuclear wavepackets created by coherent excitation of an autoionized and predissociated 'complex' resonance in H2 are studied theoretically using time-dependent multichannel quantum defect theory. The calculations predict that quantum beats between the components of the complex resonance interfere with Rydberg wavepacket (Kepler) motion to yield characteristic 'mixed' flux patterns in the observable time-dependent ionization and dissociation signals.

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The Electronic Structure of CaCl: Calculation by R Matrix and Generalized Quantum Defect Theory.

The electronic spectrum of CaCl has been calculated using the variational eigenchannel R-matrix method combined with generalized multichannel quantum defect theory. The motion of the unpaired (Rydberg) electron is represented as a double scattering process on the closed-shell Ca(++) and Cl(-) core ions. Electron penetration into Ca(++) is taken into account as well as polarization effects. The partial saturation of the Cl(-) free-ion polarizability is evaluated on the basis of an ab initio calculation of the dipole and quadrupole moments of the CaCl(+) ion core. The calculations reproduce the effective principal quantum numbers nu of the experimentally known states (including the ground state) to within approximately 0.04. States with high-orbital angular momentum up to l = 6 are predicted. Copyright 1999 Academic Press.

Journal Article↗