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C N Likos

Publications and source records attributed to C N Likos.

20 records · Page 2Linked to original sources

Sedimentation profiles of systems with reentrant melting behavior.

We examine sedimentation density profiles of star polymer solutions as an example of colloidal systems in sedimentation equilibrium that exhibit reentrant melting in their bulk phase diagram. Phase transitions between a fluid and a fluid with an intercalated solid are observed below a critical gravitational strength alpha*. Characteristics of the two fluid-solid interfaces in the density profiles occurring in Monte Carlo simulations for alpha<alpha* are in agreement with scaling laws put forth in the framework of a phenomenological theory. Furthermore, we detect density oscillations at the fluid-gas interface at high altitudes for high-gravitational fields, which are verified with density-functional theory and should be observable in surface scattering experiments.

Journal Article↗

Criterion for determining clustering versus reentrant melting behavior for bounded interaction potentials.

We examine in full generality the phase behavior of systems whose constituent particles interact by means of potentials that do not diverge at the origin, are free of attractive parts, and decay fast enough to zero as the interparticle separation r goes to infinity. By employing a mean field-density functional theory which is shown to become exact at high temperatures and/or densities, we establish a criterion that determines whether a given system will freeze at all temperatures or it will display reentrant melting and an upper freezing temperature.

Journal Article↗