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C Ybert

Publications and source records attributed to C Ybert.

4 recordsLinked to original sources

Slippage of water past superhydrophobic carbon nanotube forests in microchannels.

We present in this Letter an experimental characterization of liquid flow slippage over superhydrophobic surfaces made of carbon nanotube forests, incorporated in microchannels. We make use of a particle image velocimetry technique to achieve the submicrometric resolution on the flow profile necessary for accurate measurement of the surface hydrodynamic properties. We demonstrate boundary slippage on the Cassie superhydrophobic state, associated with slip lengths of a few microns, while a vanishing slip length is found in the Wenzel state when the liquid impregnates the surface. Varying the lateral roughness scale L of our carbon nanotube forest-based superhydrophobic surfaces, we demonstrate that the slip length varies linearly with L in line with theoretical predictions for slippage on patterned surfaces.

Journal Article↗

Probing the nanohydrodynamics at liquid-solid interfaces using thermal motion.

We report on a new method to characterize nanohydrodynamic properties at the liquid-solid interface relying solely on the measurement of the thermal motion of confined colloids. This equilibrium measurement of surface properties--equivalent in spirit to the passive microrheology technique used for bulk properties--is able to achieve nanometric resolution on the slip length measurement. Exploring the "zero shear rate" limit, it rules out shear rate threshold to slip effects and extends the range over which slip lengths are shown to be flow independent. Avoiding the nucleation of gas pockets (nanobubbles) through external forcing, it validates the theoretical picture for intrinsic liquid-solid interfaces, reporting nanometric slip lengths (b=18+/-5 nm) only in nonwetting situations, opening the route to quantitative study on more complex surfaces with combined effects of nonwettability and roughness.

Journal Article↗

Electrically induced microflows probed by fluorescence correlation spectroscopy.

We report on the experimental characterisation of electrically induced flows at the micrometer scale through Fluorescence Correlation Spectroscopy (FCS) measurements. We stress the potential of FCS as a useful characterisation technique in microfluidics devices for transport properties cartography. The experimental results obtained in a model situation are in agreement with previous calculations (F. Nadal, F. Argoul, P. Kestener, B. Pouligny, C. Ybert, A. Ajdari, Eur. Phys. J. E 9, 387 (2002)) predicting the structure and electric-field dependency of the induced flow. Additionally, the present study evidences a complex behaviour of the probe nanobeads under electric field whose precise understanding might prove relevant for situations where nano-objects interact with an external electric field.

Electrochemistry↗

Electrically induced flows in the vicinity of a dielectric stripe on a conducting plane.

We report a theoretical and experimental study of the hydrodynamic flow induced by an a.c. electric field in the vicinity of a dielectric stripe deposited on a conducting plate. In the theoretical part, we model the stripe as a small change of the surface capacitance of the plate, and a perturbative approach is used to perform the calculations. This approach predicts an outwards rectified electro-osmotic slip along the surface that generates two steady counter-rotating rolls, the size of which decreases with the frequency. In the experimental section, we use tracers to determine the structure of the flow and investigate its dependence on the frequency and the amplitude of the applied voltage. The structure and amplitude of the observed flow compares satisfactorily with the theoretical analysis. This could guide the design of surface-controlled flows and help to understand the collective behavior of colloids near electrodes.

Journal Article↗