Biomedical subjects

Cathrine Frandsen

Publications and source records attributed to Cathrine Frandsen.

3 recordsLinked to original sources

PubMed2005

Spin rotation in alpha-Fe2O3 nanoparticles by interparticle interactions.

Nanoparticles of alpha-Fe2O3 (hematite) typically have the sublattice magnetization directions in the hexagonal (001) plane below the Ne el temperature. By use of Mo ssbauer spectroscopy we have found that for agglomerated particles the sublattice magnetization may be rotated of the order of 15 degrees out of plane, depending on the particle size. The spin rotation can be explained by exchange interaction between neighboring particles with nonparallel (001) planes. The results imply that interparticle interactions can lead to spin directions deviating from the easy axis defined by the magnetic anisotropy.

Journal Article↗

PubMed2004

Interparticle interactions in agglomerates of alpha-Fe2O3 nanoparticles: influence of grinding.

We have chemically prepared a sample of antiferromagnetic alpha-Fe2O3 nanoparticles by a gel-sol technique. Mössbauer spectra of the as-prepared sample showed that superparamagnetic relaxation was suppressed due to strong magnetic interparticle interactions even at room temperature. However, subsequent grinding of the sample by hand in a mortar for some minutes resulted in fast superparamagnetic relaxation of some of the particles. The effect was even more dramatic if the alpha-Fe2O3 powder was ground for a longer time or together with nonmagnetic eta-Al2O3 nanoparticles. Similar effects were found after low-energy ball milling. Thus it is found that the agglomeration of the nanoparticles during preparation under wet conditions results in strong magnetic interparticle interaction, but a relatively gentle mechanical treatment is sufficient to break up the agglomerates, resulting in much weaker interactions. We show that these effects can also be seen when a soil sample containing magnetic nanoparticles is ground.

Journal Article↗

PubMed2004

Thermoinduced magnetization in nanoparticles of antiferromagnetic materials.

We show that there is a thermoinduced contribution to the magnetic moment of nanoparticles of antiferromagnetic materials. It arises from thermal excitations of the uniform spin-precession mode, and it has the unusual property that its magnitude increases with increasing temperature. This has the consequence that antiferromagnetism is nonexistent in nanoparticles at finite temperatures and it explains magnetic anomalies, which recently have been reported in a number of studies of nanoparticles of antiferromagnetic materials.

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