Biomedical subjects

Charles Rosenblatt

Publications and source records attributed to Charles Rosenblatt.

At least 19 recordsLinked to original sources

PubMed2006

Bend-induced melting of the smectic-A phase: analogy to a type-I superconductor.

Using an atomic force microscope to nanopattern a substrate for liquid crystal alignment, a bend distortion is imposed on a liquid crystal. In regions of large bend the smectic-A phase melts into the nematic phase, and the width of the melted region is measured as a function of temperature. The results are consistent with type-I superconducting (nematic-smectic-A) behavior, wherein a large magnetic field (bend or twist distortion) induces an order to disorder transition. A model that accounts for non-mean-field behavior is presented.

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PubMed2006

Rubbing-induced anisotropy of long alkyl side chains at polyimide surfaces.

Molecular organization at polyimide surfaces used as alignment layers in liquid crystal displays was investigated using vibrational sum frequency generation (SFG) spectroscopy. We focus on the orientation of the long alkyl side groups at the polymer surface using polarization-selected SFG spectra of the CH(3)- and CH(2)-stretch modes of the side chain. Mechanical rubbing and baking, an accepted industrial procedure used to produce pretilt of the liquid crystal, was found to induce pronounced azimuthal anisotropy in the orientational distribution of the alkyl side chains. Orientational analysis of the SFG vibrational spectra in terms of the azimuthal and tilt angles (in and out of plane, respectively) of the alkyl side chains shows their preferential tilt along the rubbing direction, with the azimuthal distribution narrower for stronger rubbed polymer samples.

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PubMed2006

Quasidivergent nematic surface electroclinic effect.

A polyimide coated substrate is treated so that vertical liquid crystal alignment (theta=0) obtains over the temperature range T(NA)< T < T(a), where T(NA) is the nematic-smectic-A transition temperature. When the cell is filled with a chiral liquid crystal whose helical pitch is unwound (surface stabilized), application of an in-plane electric field for T(NA)< T < T(a) induces a nonzero polar tilt theta proportional to E of the liquid crystal director at the surface, where the tilted orientation propagates elastically into the bulk. On heating toward T(a), this surface electroclinic response becomes large, corresponding to the onset of a surface tilt transition at T(a) from theta=0 to nonzero theta.

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PubMed2006

Rayleigh-Taylor instability for immiscible fluids of arbitrary viscosities: a magnetic levitation investigation and theoretical model.

A magnetic field gradient was used to draw down a low density paramagnetic fluid below a more dense fluid in a Hele-Shaw cell. On turning off the field a Rayleigh-Taylor instability was observed in situ, and the growth of the most unstable wave vector was measured versus time. A theory for the instability that permits different viscosities for two immiscible fluids was developed, and good agreement was found with the experimental results. The technique of magnetic levitation promises to broaden significantly the accessible parameter space of gravitational interfacial instability experiments.

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PubMed2005

Smectic tilt susceptibility: anharmonic behavior in surface-induced smectic layers above the nematic--smectic-a transition temperature.

Fréedericksz transition measurements were performed on the Merck liquid crystal SCE12R. The results were used to determine the quartic contribution to the free energy associated with molecular tilt relative to the layer normal in the surface-induced smectic layers above the nematic-smectic-A transition temperature T(NA) . Both the quadratic and quartic coefficients are consistent with the scaling relation (T- T(NA))(-3nu) , where nu is the correlation length critical exponent, and their ratio was approximately constant with T . The dielectric constants, the refractive indices, and the bend elastic constant for SCE12R also are reported.

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PubMed2005

Effect of flexible bimesogen dopant on the stability of the anticlinic liquid-crystal phase.

Small quantities of the floppy bimesogen di(4PPB5)3Si were dissolved in an anticlinic liquid crystal consisting of a mixture of left-handed and right-handed TFMHPOBC, with enantiomer excess X=0.2 . The bimesogen dopant was found to promote anticlinic order with an anticlinic interaction coefficient per molecule udopant smaller than, but of the same order as, that of the rigid bent-core dopant P-7PIMB. For both dopants udopant was found to be much larger than that due to a pair of TFMHPOBC molecules in adjacent layers. The results are examined in terms of both the flexibility of the group linking the two legs of each dopant, as well as their chemical structure.

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PubMed2005

Polar anchoring strength of a tilted nematic: confirmation of the dual easy axis model.

The polar anchoring strength coefficient W and polar pretilt angle theta0 were measured simultaneously for the liquid crystal pentylcyanobiphenyl at a rubbed polyimide alignment layer that is ordinarily used for vertical alignment. It was found that W proportional theta(2)0 over the range 0 degrees < or =theta0 less or similar to 35 degrees . The results provide a confirmation of the dual easy axis model, wherein the liquid crystal director adopts an equilibrium orientation theta0 at the substrate that is determined by competition between a pair of preferred orientation directions.

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PubMed2004

Bent-core dopant in a liquid crystal having a reentrant synclinic phase.

Small quantities of the bent-core mesogen P-7PIMB were dissolved in an anticlinic liquid crystal consisting of a mixture of left- and right-handed TFMHPOBC, with enantiomer excess X=0.2. The bent-core dopant promotes anticlinic order at higher temperatures, but becomes less effective in suppressing the synclinic phase at the reentrant synclinic transition due to an orientational transition of the dopant within the calamitic TFMHPOBC matrix. Measurements of the anticlinic-synclinic electric-field switching threshold as a function of temperature and dopant concentration facilitate a determination of the component of the anticlinic interaction coefficient U that is due to the bent-core dopant. It is found that the value of U per bent-core molecule is much larger than the corresponding value for a pair of TFMHPOBC molecules in adjacent smectic layers.

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PubMed2004

Twist elasticity and anchoring in a lamellar nematic phase.

Electro-optic measurements were performed on a lamellar nematic phase in which the mesogenic moieties lie in lamellae that are separated by partially perfluorinated side groups. The twist elastic constant K22, viscosity gamma(1), and the quadratic and quartic anchoring strength coefficients are reported. K22 and gamma(1) are found to be considerably smaller than that of typical three-dimensional nematics. The small K22 is due to the greatly weakened interactions between the spatially separated lamellae.

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PubMed2003

Light scattering investigation above the nematic-smectic-A phase transition in binary mixtures of calamitic and bent-core mesogens.

Quasielastic light scattering measurements were performed in the nematic phase of mixtures consisting of the calamitic mesogen 8OCB doped with small concentrations of the bent-core molecule P-7PIMB. It was found that the regular part of the bend elastic constant decreases strongly with dopant concentration X. Close to the nematic-smectic-A phase transition temperature, the divergent part of the bend elastic constant, which is proportional to the bare correlation length xi(0)(||) parallel to the layer normal, also decreases rapidly with X. The effect of the dopant on xi(0)(||) is examined in brief theoretically.

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PubMed2003

Surface-induced molecular tilt above the smectic-A-smectic-C phase transition in a nonchiral liquid crystal.

A polyimide-coated substrate was rubbed in such a way as to possess two competing easy axes for liquid crystal alignment. On cooling a homeotropically aligned liquid crystal through the smectic-A phase toward the smectic-C phase transition, an increasing tilt of the molecules relative to the layer normal was observed. The tilt was localized to within a smectic-C correlation length of the interface, and was found to increase monotonically with the rubbing strength associated with the preparation of the polyimide surface. The results are discussed in light of the dual easy axis model [T. Shioda et al., Phys. Rev. E 67, 041706 (2003)], and suggest that the two easy axes are not mutually orthogonal.

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PubMed2003

Reentrant synclinic phase in an electric-field-temperature-phase diagram for enantiomeric mixtures of an antiferroelectric liquid crystal.

The threshold electric field E(th) for a transition from the anticlinic to the synclinic phase of enantiomeric mixtures of the liquid crystal TFMHPOBC was measured as a function of temperature T and enantiomeric excess X. For small X the phase boundary curve on a temperature-electric-field phase diagram exhibits the phase sequence synclinic-anticlinic-reentrant synclinic on decreasing the temperature. At one point along the curve the quantity dT/dE--> infinity. For large values of enantiomeric excess a reentrant phase is not observed. The results are discussed using a simple phenomenological theory that accounts for layer-layer interactions, such that the electric-field-induced transition to the synclinic phase, although completed by solitary-wave propagation, is facilitated by a percolation mechanism.

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PubMed2003

Continuous nematic anchoring transition due to surface-induced smectic order.

A continuous transition from tilted to homeotropic alignment at an interface is observed at a temperature T(a) for a nematic liquid crystal on cooling toward the nematic-smectic-A phase transition temperature. T(a) is found to depend on the treatment of the substrate. The behavior is examined theoretically in terms of a pair of competing easy axes (homeotropic and planar) and the tilt elasticity associated with the growth of surface-induced smectic order.

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PubMed2003

Transverse surface-induced polarization at the interface between a chiral nematic liquid crystal and a substrate.

A chiral nematic liquid crystal that is tilted by an angle theta(i) with respect to a substrate is subjected to an ac electric field at frequency omega applied parallel to the substrate. The nematic director is found to oscillate azimuthally about the normal to the liquid crystal-substrate interface at frequency omega, indicating that a nonzero polarization perpendicular to the molecular tilt plane exists at the interface. The interfacial polarization, anchoring strength coefficient, and bulk viscosity are obtained by measurements of the oscillation amplitude as a function of omega.

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PubMed2003

Apparent tricritical behavior at a nearly second-order nematic-isotropic phase transition of a cyclic liquid crystalline trimer.

The cyclic liquid crystalline trimer TPB-(c)9(3) was investigated by optical retardation and Fréedericksz techniques within a few tens of millikelvins of the superheating limit of the nearly second-order nematic-isotropic phase transition. Both the optical retardation and the Fréedericksz bend threshold voltage are in good agreement with tricritical behavior for the transition.

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PubMed2002

Depression of the nematic-isotropic phase transition temperature at nanopatterned surfaces.

A spatially varying herringbone pattern with an easy axis alternating in angle between 0 and psi and having a period of 200 nm was scribed into a polyimide-coated substrate. The depression of the nematic-isotropic transition temperature for a nematic layer at the patterned surface relative to its value at a uniformly rubbed surface was investigated as a function of psi for 15 < psi < 88 degrees. It was found that the depression of the transition temperature increases with psi, up to approximately 7 mK at psi=88 degrees. A simple model was developed that includes not only elasticity, but also anchoring effects at the polyimide. The model, which is used to calculate the thickness of the nematic layer, indicates that anchoring-rather than elastic-effects play the dominant role in the depression of the layer's transition temperature.

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PubMed2002

First-order Fréedericksz transition above the nematic-smectic-a phase transition.

The Fréedericksz transition is investigated for thin homeotropic cells of a negative dielectric anisotropy liquid crystal above its nematic-smectic-A phase transition temperature in a spatially uniform electric field. For very thin cells, a crossover from second- to first-order Fréedericksz behavior is observed; no additional fields are necessary. The results are consistent with the theory of Shi [Liq. Cryst. 29, 121 (2002)]].

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PubMed2002

Disruption of surface-induced smectic order by periodic surface corrugations.

A Fréedericksz transition measurement is reported for a liquid crystal cell composed of surfactant-coated substrates. One substrate was locally scribed with the stylus of an atomic force microscope to create a nanoscopic grooved structure. The Fréedericksz threshold voltage was found to be smaller in the scribed region than in the unscribed region, indicating that the corrugated surface disrupts surface-induced smectic order, and that the effect grows toward the nematic-smectic-A transition temperature T(NA) in conjunction with the smectic correlation length.

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