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Christian Maes

Publications and source records attributed to Christian Maes.

4 recordsLinked to original sources

Fluctuation symmetries for work and heat.

We consider a particle dragged through a medium at constant temperature as described by a Langevin equation with a time-dependent potential. The time dependence is specified by an external protocol. We give conditions on potential and protocol under which the fluctuations of the dissipative work satisfy an exact symmetry for all times. We also present counterexamples to that fluctuation theorem when our conditions are not satisfied. Finally, we consider the dissipated heat, which differs from the work by a temporal boundary term. We explain why there is a correction to the standard fluctuation theorem due to the unboundedness of that temporal boundary. However, the corrected fluctuation relation has again a general validity.

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Time-symmetric fluctuations in nonequilibrium systems.

For nonequilibrium steady states, we identify observables whose fluctuations satisfy a general symmetry and for which a new reciprocity relation can be shown. Unlike the situation in recently discussed fluctuation theorems, these observables are time-reversal symmetric. That is essential for exploiting the fluctuation symmetry beyond linear response theory. In addition to time reversal, a crucial role is played by the reversal of the driving fields that further resolves the space-time action. In particular, the time-symmetric part in the space-time action determines the second order effects of the nonequilibrium driving.

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Enstrophy dissipation in two-dimensional turbulence.

Insight into the problem of two-dimensional turbulence can be obtained by an analogy with a heat conduction network. It allows the identification of an entropy function associated with the enstrophy dissipation and that fluctuates around a positive (mean) value. While the corresponding enstrophy network is highly nonlocal, the direction of the enstrophy current follows from the Second Law of Thermodynamics. An essential parameter is the ratio of the intensity of driving as a function of wave number , to the dissipation strength , where is the viscosity. The enstrophy current flows from higher to lower values of , similar to a heat current from higher to lower temperature. Our probabilistic analysis of the enstrophy dissipation and the analogy with heat conduction thus complements and visualizes the more traditional spectral arguments for the direct enstrophy cascade. We also show a fluctuation symmetry in the distribution of the total entropy production which relates the probabilities of direct and inverse enstrophy cascades.

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Quantum version of free-energy--irreversible-work relations.

We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main ingredient is the identification of work depending on the quantum history of the system and the proper definition of various quantum ensembles over which the averages should be made. We also discuss a number of different regimes that have been considered by other authors and which are unified in the present set-up. In all cases, quantum or classical, it is a general relation between heat and time-reversal that makes the Jarzynski relation so universally valid.

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