Biomedical subjects

Christopher R Webster

Publications and source records attributed to Christopher R Webster.

3 recordsLinked to original sources

PubMed2005

Measuring methane and its isotopes 12CH4, 13CH4, and CH3D on the surface of Mars with in situ laser spectroscopy.

In light of the recent discovery of methane on Mars and its possible biological origin, a strategy is described for making in situ measurements of methane and its isotopes on the surface of Mars by laser spectroscopy in the 3.3-microm wavelength region. An instrument of reasonable mass (approximately 1 lb) and power (few watts) is capable of measuring mixing ratios down to 0.1 part per 10(9) by volume, a hundred times lower than recently reported observations. Making accurate measurements of 13CH4 and CH3D will be more difficult. For measuring delta13C to 10/1000 and deltaD to 50/1000, sample preconcentration will be required to approximately 3 parts per 10(6) by volume for delta13C and to approximately 40 parts per 10(6) by volume for deltaD. This need would be mitigated by the discovery of larger local abundances of methane near the source regions.

Journal Article↗

PubMed2004

Mars laser hygrometer.

We have designed and built a miniature near-IR tunable diode laser (TDL) spectrometer for measuring in situ the water vapor mixing ratio either in the Martian atmosphere or thermally evolved from Martian soil or ice samples. The laser hygrometer uses a thermoelectrically cooled single-mode distributed-feedback TDL at 1.87 microm to scan over a selected vibration-rotation line of both H2O and CO2 near 5327.3 cm(-1). A working prototype that weighs only 230 g has been built and used to generate spectra whose analysis demonstrates precision sensitivities as fine as 1 part in 10(6) by volume in 1 s or 0.1 part in 10(6) in 10 s at Martian pressures and temperatures. Absolute uncertainties of approximately 5% are calculated.

Journal Article↗

PubMed2003

Water isotope ratios D/H, 18O/16O, 17O/16O in and out of clouds map dehydration pathways.

Water isotope ratios have been measured by laser absorption spectroscopy in and out of cirrus clouds formed in situ and convectively generated in anvils over subtropical regions. Water vapor in the tropical and subtropical upper troposphere shows a wide range of isotopic depletion not observed previously. The range suggests that dehydration of upper tropospheric air occurs both by convective dehydration and by gradual dehydration mechanisms. Twenty-five percent of upper tropospheric water sampled is in ice particles whose isotopic signatures are used to identify those grown in situ from those lofted from below.

Journal Article↗