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Biomedical subjects

D Glindemann

Publications and source records attributed to D Glindemann.

6 recordsLinked to original sources

Health and aesthetic impacts of copper corrosion on drinking water.

Traditional research has focused on the visible effects of corrosion--failures, leaks, and financial debits--and often overlooked the more hidden health and aesthetic aspects. Clearly, corrosion of copper pipe can lead to levels of copper in the drinking water that exceed health guidelines and cause bitter or metallic tasting water. Because water will continue to be conveyed to consumers worldwide through metal pipes, the water industry has to consider both the effects of water quality on corrosion and the effects of corrosion on water quality. Integrating four key factors--chemical/biological causes, economics, health and aesthetics--is critical for managing the distribution system to produce safe water that consumers will use with confidence. As technological developments improve copper pipes to minimize scaling and corrosion, it is essential to consider the health and aesthetic effects on an equal plane with chemical/biological causes and economics to produce water that is acceptable for public consumption.

Copper↗

Production of class A biosolids with anoxic low dose alkaline treatment and odor management.

The feasibility of full-scale anoxic disinfection of dewatered and digested sludge from Winnipeg, Manitoba with low lime doses and lagoon fly ash was investigated to determine if a class A product could be produced. Lime doses of 50 g, 100 g, and 200 g per kg of biosolids (dry) were used along with fly ash doses of 500 g, 1,000 g, and 1,500 g per kg of biosolids (dry). The mixed product was buried in eight-10 cubic metre trenches at the West End Water Pollution Control Center in Winnipeg. The trenches were backfilled with dirt and trapped to simulate anoxic conditions. Sampling cages were packed with the mixed product and pathogens non-indigenous to Winnipeg's biosolids. The cages were buried amongst the mixed biosolids in the trench. The non-indigenous pathogens spiked in the laboratory were the helminth Ascaris suum and the enteric virus reovirus. Samples were removed at days 12, 40, 69, 291, and 356 and were tested for the presence of fecal Coliform, Clostridium perfringens spores, Ascaris suum eggs, and reovirus. The pH, total solids, and free ammonia content of the mixed product were also determined for each sample. Odor was quantified for samples at both 291 and 356 days. Fecal Coliform bacteria and reovirus were completely inactivated for doses as low as 100 g lime per kg biosolids (dry) and 50 g lime + 500 g fly ash per kg biosolids (dry). Spores of the bacteria C. perfringens experienced a 4-log reduction when treated with 100 g lime per kg biosolids and a 5-log reduction when treated with doses as low as 50 g lime + 500 g fly ash per kg biosolids (dry) after 69 days. Ascaris eggs were completely inactivated in 5 gram packets for all treatments involving 100 g lime per kg biosolids (dry) after 69 days. Class A pathogen requirements were met for all treatments involving a lime dose of at least 100 g per kg biosolids. The odor potential from the produced biosolids is also assessed.

Alkalies↗

Phosphorus cycling through phosphine in paddy fields.

Phosphine emission fluxes from paddy fields, phosphine ambient levels in air, and the vertical profile of matrix-bound phosphine in soil have been measured throughout the growing season of rice in Beijing, China. It was found that both the seasonal and diurnal emission fluxes and ambient levels fluctuate significantly. During the drainage period, phosphine released from the soil with the highest diurnal average flux on the first period of drainage (approx. 17.7 ng m(-2) h(-1)), whereas its highest ambient level (approx. 250 ng m(-3)) occurred at 06.00 h. During the flooded period, phosphine emission was low, and the peaks of phosphine emissions occurred at midnight. The average flux of PH3 emission for the whole season was found to be approximately 1.78 ng m(-2) h(-1). The mass fraction of matrix-bound phosphine is approximately 0.18 approximately 1.42 x 10(-7) (m/m) part of organic phosphorus or 3.4 approximately 9.2 x 10(-9) (m/m) part of total phosphorus in paddy soil. The amount of phosphine emitted to the atmosphere was only a small fraction of the phosphine that remained in the soil in the matrix-bound form. Soil serves both as the source and the sink of PH3.

Air Pollutants↗

Chemical reduction of phosphate on the primitive earth.

If phosphorus played a role in the origin of life, some means of concentrating micromolar levels of phosphate (derived from the calcium phosphate mineral apatite), must first have been available. Here we show that simulated (mini)lightning discharges in model prebiotic atmospheres, including only minimally reducing ones, reduce orthophosphates, including apatite, to produce substantial yields of phosphite. Electrical discharges associated with volcanic eruptions could have provided a particularly suitable environment for this process. Production of relatively soluble and reactive phosphite salts could have supplied a pathway by which the first phosphorus atoms were incorporated into (pre)biological systems.

Apatites↗

Balancing phosphine in manure fermentation.

The evolution of phosphine gas during the anaerobic batch fermentation of fresh swine manure was detected and correlated to the production of methane and hydrogen sulphide. A close temporal relationship between phosphine liberation and methane formation was found. However, the gaseous phosphine released from manure during fermentation only represents a tiny fraction of the overall phosphine balance. The majority of phosphine is captured in solid manure constituents. This matrix-bound phosphine is eliminated by more than 50% during anaerobic batch-fermentation. Seasonally determined phosphine concentrations in biogas and manure from two large-scale manure treatment plants also revealed net losses of phosphine in fermentation. Consequently, manure has to be considered more as a sink of phosphine rather than a phosphine-generating medium. Furthermore, a close relationship between phosphine in the feed of swine and manure of these swine was observed, implying that phosphine residues in the feed (possibly as a result of grain fumigation) represent an important source of phosphine in manure technologies that is relevant before the faecals of swine enter manure treatment plants.

Air Pollutants↗

Spontaneous emission of phosphane from animal slurry treatment processing.

The degree of the emission of the mutagenic phosphane from animal slurry have become an issue of hygienic which so far has not been investigated. This work clearly detects spontaneously emitted free phosphane from animal slurry for the first time and correlates the degree of its emission with different disposal technologies. The subjects of the investigations are the simple storage process and processes involving biogas plants for the digestion both of pig and cattle slurry. Pig slurry generates about one magnitude more phosphane than cattle slurry. The maximum concentration detected in putrefaction gas was 14621 ppt(v/v). Putrefaction gas samples from fresh fecal slurry in primary (mediary storage) tanks followed by storage basins and sedimenters contains the highest concentrations. The mainly methanogenic biogas process generates the smallest concentrations but the highest fluxes of phosphane. Fluxes and concentrations in open basins are significantly higher during summer than in winter. The correlation of phosphane and dimethyldisulfide concentrations indicates that primary lytic processes play a role in the liberation of phosphane. Individual samples of the emission in air give a maximum value of 35 ppt. By comparison, measurement of phosphane in Hungarian digester gas from municipal sewage treatment show that maximum concentrations could be some orders of magnitude higher. Therefore the data base for phosphane from animal slurry must in future be expanded. The results of analysis so far achieved cannot be interpreted from either a human or veterinary medical viewpoint.

Air Pollutants, Occupational↗