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D M Lawler

Publications and source records attributed to D M Lawler.

4 recordsLinked to original sources

Turbidity dynamics during spring storm events in an urban headwater river system: the Upper Tame, West Midlands, UK.

Turbidity is an important water quality variable, through its relation to light suppression, BOD impact, sediment-associated contaminant transport, and suspended sediment effects on organisms and habitats. Yet few published field investigations of wet-weather turbidity dynamics, through several individual and sequenced rainstorms in extremely urbanised headwater basins, have emerged. This paper aims to address this gap through a turbidity analysis of multiple storm events in spring 2001 in an urban headwater basin (57 km2) of the River Tame, central England, the most urbanised basin for its size in the UK ( approximately 42%). Data were collected at 15-min frequency at automated monitoring stations for rainfall, streamflow and six water quality variables (turbidity, EC, temperature, DO, pH, ammonia). Disturbance experiments also allowed estimates of bed sediment storage to be obtained. Six important and unusual features of the storm event turbidity response were apparent: (1) sluggish early turbidity response, followed by a turbidity 'rush'; (2) quasi-coincident flow and turbidity peaks; (3) anti-clockwise hysteresis in the discharge-turbidity relationship on all but one event, resulting from Falling-LImb Turbidity Extensions (FLITEs); (4) increases in peak turbidity levels through storm sequences; (5) initial micro-pulses (IMP) in turbidity; and (6) secondary turbidity peaks (STP) or 'turbidity shoulders' (TS). These features provided very little evidence of a true 'first-flush' effect: instead, substantial suspended solids transport continued right through the flow recessions, and little storm-event sediment exhaustion was evident. A new, dimensionless, hysteresis index, HI(mid), is developed to quantify the magnitude and direction of hysteresis in a simple, clear, direct and intuitive manner. This allowed the degree of departure from the classic 'first-flush', clockwise hysteresis models to be assessed. Of the 15 turbidity events considered, 10 coincided with ammonia spikes of up to 6.25 mg l(-1) at Water Orton (the downstream station): this suggests that spills from combined sewer overflows (CSO) or waste water treatment works (WwTWs) are significant in the throughput of turbid waters here. Substantial ammonia peaks related most strongly to total storm rainfall receipt, of four rainfall variables considered, and significant ammonia peaks were generated even from low-magnitude storms (rainfall totals <4 mm), indicating that spills are a frequent occurrence. Local bed sediment stores appear to be limited, suggesting that other distal sediment sources, such as road networks and old mineworkings are possibly more important. Biofilms may also play a part in delaying sediment release until late in the hydrograph, and in suppressing late spring turbidity levels. Existing first-flush models appear to be an oversimplification here. Such urban headwater basin responses can provide useful insights into the generation of contaminant waves, and offer vital early-warning systems for pollution events propagating downstream.

Ammonia↗

Measuring sediment exchange rates on an intertidal bank at Blacktoft, Humber Estuary, UK.

Results from a suite of Photo Electronic Erosion Pins (PEEPs) and manual pins installed on an intertidal bank at Blacktoft, near the confluence of the Rivers Trent and (Yorkshire) Ouse, UK are presented for summer 1997 (1 May-28 September). These reveal a pattern of erosion and deposition, which can be related to variations in tidal range, freshwater flow and wind speed over the period. During spring tides, greater resuspension of bed sediment leads to a greater availability of sediment in the water column for deposition on the bank. High wind speeds cause greater erosion of material from the bank due to wind-induced wave action. These processes of sediment exchange are also modified by the effects of biological activity on the sediment and of consolidation. It was demonstrated that the mean daily change in elevation of the upper part of the bank at Blacktoft was approximately 11 mm, which is two-three-fold less than the equivalent figure measured by a similar method at Burringham on the River Trent. It is thought that this difference is due to the effects of a greater concentration of suspended sediment settling onto the banks at Burringham, which are also subject to greater erosion due to their steeper slope. Results from a longer and more widespread survey of eight other intertidal banks in the Trent-Ouse Estuary system suggest that deposition and erosion occur in phase on all intertidal banks within the study area. Intertidal banks towards the upstream end of the system show much less variation in bank level than those further downstream.

Journal Article↗

Antimicrobial 3-methyleneflavanones.

The antimicrobial activity previously attributed to flavanone Mannich bases was found to be due to their breakdown products, 3-methyleneflavanones. Among the latter compounds, highest potency was observed when the flavanone phenyl ring contained bromine or chlorine substituents. 3-Methylene-2-phenylflavanone (8) was synthesized and shown to be equal to hexachlorophene in tests against representative Gram-positive microorganisms.

Anti-Bacterial Agents↗