D M Mitrinović | PubMed Health

PubMed2001

X-ray study of oil-microemulsion and oil-water interfaces in ternary amphiphilic systems.

We present x-ray reflectivity and diffuse scattering measurements from the interfaces between oil-rich and microemulsion bulk phases and between oil-rich and water-rich phases in three-component microemulsion systems (consisting of water, alkane, and C(i)E(j), where the last represents n-alkyl polyglycol ether with i=4,6,10 and j=1,2,4). The x-ray measurements are analyzed with a two-parameter fit that determines the interfacial roughness, varying from 25 A to 160 A, and the interfacial tension, varying from 1.4 mN/m to 0.03 mN/m, for these samples. Although a nonmonotonic profile at the oil-microemulsion interface is not observed, these measurements exclude the presence of oscillating profiles with repeat distances greater then 500 A.

Journal Article↗

PubMed2000

Noncapillary-wave structure at the water-alkane interface.

Synchrotron x-ray reflectivity is used to study the interface between bulk water and bulk n-alkanes with carbon numbers 6 through 10, 12, 16, and 22. For all interfaces, except the water-hexane interface, the interfacial width disagrees with the prediction from capillary-wave theory. The variation of interfacial width with carbon number can be described by combining the capillary-wave prediction for the width with a contribution from intrinsic structure. This intrinsic structure is determined by the gyration radius for the shorter alkanes and by the bulk correlation length for the longer alkanes.

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