Biomedical subjects

D Tomanek

Publications and source records attributed to D Tomanek.

10 recordsLinked to original sources

PubMed2000

Photogalvanic effects in heteropolar nanotubes

We show that an electrical shift current is generated when electrons are photoexcited from the valence to conduction bands on a BN nanotube. This photocurrent follows the light pulse envelope and its symmetry is controlled by the atomic structure of the nanotube. We find that the shift current has an intrinsic quantum mechanical signature in which the chiral index of the tube determines the direction of the current along the tube axis. We identify the discrete lattice effects in the tangent plane of the tube that lead to an azimuthal component of the shift current. The nanotube shift current can lead to ultrafast optoelectronic and optomechanical applications.

Journal Article↗

PubMed2000

Unusually high thermal conductivity of carbon nanotubes

Combining equilibrium and nonequilibrium molecular dynamics simulations with accurate carbon potentials, we determine the thermal conductivity lambda of carbon nanotubes and its dependence on temperature. Our results suggest an unusually high value, lambda approximately 6600 W/m K, for an isolated (10,10) nanotube at room temperature, comparable to the thermal conductivity of a hypothetical isolated graphene monolayer or diamond. Our results suggest that these high values of lambda are associated with the large phonon mean free paths in these systems; substantially lower values are predicted and observed for the basal plane of bulk graphite.

Journal Article↗

PubMed2000

Fractional quantum conductance in carbon nanotubes

Using a scattering technique based on a parametrized linear combination of atomic orbitals Hamiltonian, we calculate the ballistic quantum conductance of multiwall carbon nanotubes. We find that interwall interactions not only block some of the quantum conductance channels, but also redistribute the current nonuniformly over individual tubes across the structure. Our results provide a natural explanation for the unexpected integer and noninteger conductance values reported for multiwall nanotubes by Stefan Frank et al. [Stefan Frank et al., Science 280, 1744 (1998)].

Journal Article↗

PubMed2000

Orientational melting in carbon nanotube ropes

Using Monte Carlo simulations, we investigate the possibility of an orientational melting transition within a "rope" of carbon nanotubes. When twisting nanotubes bundle up during the synthesis, orientational dislocations or twistons arise from the competition between the anisotropic intertube interactions, which tend to align neighboring tubes, and the torsion rigidity that tends to keep individual tubes straight. We map the energetics of a rope containing twistons onto a lattice gas model and find that the onset of a free "diffusion" of twistons, corresponding to orientational melting, occurs at T(OM) greater, similar160 K.

Journal Article↗

PubMed1996

Crystalline Ropes of Metallic Carbon Nanotubes

Fullerene single-wall nanotubes (SWNTs) were produced in yields of more than 70 percent by condensation of a laser-vaporized carbon-nickel-cobalt mixture at 1200degreesC. X-ray diffraction and electron microscopy showed that these SWNTs are nearly uniform in diameter and that they self-organize into "ropes," which consist of 100 to 500 SWNTs in a two-dimensional triangular lattice with a lattice constant of 17 angstroms. The x-ray form factor is consistent with that of uniformly charged cylinders 13.8 +/- 0.2 angstroms in diameter. The ropes were metallic, with a single-rope resistivity of <10(-4) ohm-centimeters at 300 kelvin. The uniformity of SWNT diameter is attributed to the efficient annealing of an initial fullerene tubelet kept open by a few metal atoms; the optimum diameter is determined by competition between the strain energy of curvature of the graphene sheet and the dangling-bond energy of the open edge, where growth occurs. These factors strongly favor the metallic (10,10) tube with C5v symmetry and an open edge stabilized by triple bonds.

Journal Article↗

PubMed1991