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DC Swenson

Publications and source records attributed to DC Swenson.

2 recordsLinked to original sources
PubMed2000

(1E,3E,5E)-1,2,3,4,5,6-Hexafluoro-1,6-diphenylhexatriene

The title triene, C(18)H(10)F(6), was prepared via the Pd(0) coupling reaction of (E)-(1,2-difluoro-1, 2-ethenediyl)bis(tributylstannane) with (Z)-beta-iodo-alpha, beta-difluorostyrene in N,N'-dimethylformamide/tetrahydrofuran. The crystal structure shows the product to be the 1E,3E,5E isomer. Due to steric interactions between F atoms, the double bonds are not coplanar. The planes defined by the two terminal double bonds are almost perpendicular.

Journal Article↗
PubMed2000

A dicationic gallium-oxo-hydroxide cage compound

The crystal structure of hexa-&mgr;-hydroxo-dodecamethylocta-&mgr;(3)-oxo-dodecagallium(III) bis[tetrakis(pentafluorophenyl)borate(III)] chlorobenzene disolvate dihydrate, [Ga(12)(CH(3))(12)(&mgr;(3)-O)(8)(&mgr;-OH)(6)](C(24)F(20)B)(2). 2C(6)H(5)Cl.2H(2)O, is reported. The gallium-oxo-hydroxide dication is located on an inversion center and adopts a cage structure composed of 12 fused Ga(3)O(3) rings and is associated with the hydrate molecules and the [B(C(6)F(5))(4)](-) anions through hydrogen bonds and one O-H.pi-ring interaction. Disordered chlorobenzene solvent molecules are also present in the crystal structure.

Journal Article↗