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DP Shelton

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Librons observed in liquid acetonitrile by hyper-rayleigh scattering

Hyper-Rayleigh scattering intensity ratios I(VV)/I(VH) in the range 9-26 are observed for liquid acetonitrile (CH 3CN), inconsistent with localized modes of motion in an isotropic fluid. The observations are consistent with propagating orientational modes (librons) with frequency nu = 2 cm (-1), which scatter 71% of the light.

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Journal Article↗