Biomedical subjects

E E Mola

Publications and source records attributed to E E Mola.

7 recordsLinked to original sources

PubMed2006

Scaling properties in the average number of attempts until saturation in random sequential adsorption processes.

In the present paper we investigate the exact average number of attempts until saturation when a square lattice is ceaselessly bombarded with beta-bell (beta> or =1) particles, i.e., linear particles that require beta consecutive lattice sites to be adsorbed. When that average number is normalized with the corresponding single-particle average, a scale invariant behavior is revealed with a scaling exponent alpha=0.017 +/- 0.001, independent of beta (beta>1). The scale behavior is suggested by the branching characteristics governing the sequential random adsorption of beta-bell (beta>1) particles, which is indeed a consequence of configurational correlations.

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PubMed2005

The structure of the chiral Pt531 surface: a combined LEED and DFT study.

The structure of the chiral kinked Pt531 surface has been determined by low-energy electron diffraction intensity-versus-energy (LEED-IV) analysis and density functional theory (DFT). Large contractions and expansions of the vertical interlayer distances with respect to the bulk-terminated surface geometry were found for the first six layers (LEED: d12 = 0.44 A, d23 = 0.69 A, d34 = 0.49 A, d45 = 0.95 A, d56 = 0.56 A; DFT: d12 = 0.51 A, d23 = 0.55 A, d34 = 0.74 A, d45 = 0.78 A, d56 = 0.63 A; dbulk = 0.66 A). Energy-dependent cancellations of LEED spots over unusually large energy ranges, up to 100 eV, can be explained by surface roughness and reproduced by applying a model involving 0.25 ML of vacancies and adatoms in the scattering calculations. The agreement between the results from LEED and DFT is not as good as in other cases, which could be due to this roughness of the real surface.

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PubMed2005

How many Langmuirs are required for monolayer formation?

In the present work, we provide the exact answer to the title question employing a probabilistic approach. The average number of Langmuirs L required for monolayer formation was found to be equal to (1/i), i.e., the armonic series up to the nth term, where n is the number of adsorption sites. This result is particularly useful when a reduced number of adsorption sites is considered, such as adsorption on small terraces of nanoscopic dimensions where the value of n could be in the range of a few thousands sites. In this case, the use of integrated equations derived from the mean-field approach would provide completely misleading results.

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PubMed2004

Dielectric breakdown model for conductor-loaded and insulator-loaded composite materials.

In the present work we generalize the dielectric breakdown model to describe dielectric breakdown patterns in both conductor-loaded and insulator-loaded composites. The present model is an extension of a previous one [F. Peruani et al., Phys. Rev. E 67, 066121 (2003)] presented by the authors to describe dielectric breakdown patterns in conductor-loaded composites. Particles are distributed at random in a matrix with a variable concentration p. The generalized model assigns different probabilities P(i,k-->i('),k(')) to breakdown channel formation according to particle characteristics. Dielectric breakdown patterns are characterized by their fractal dimension D and the parameters of the Weibull distribution. Studies are carried out as a function of the fraction of inhomogeneities, p.

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PubMed2003

Dielectric breakdown model for composite materials.

This paper addresses the problem of dielectric breakdown in composite materials. The dielectric breakdown model was generalized to describe dielectric breakdown patterns in conductor-loaded composites. Conducting particles are distributed at random in the insulating matrix, and the dielectric breakdown propagates according to new rules to take into account electrical properties and particle size. Dielectric breakdown patterns are characterized by their fractal dimension D and the parameters of the Weibull distribution. Studies are carried out as a function of the fraction of conducting inhomogeneities, p. The fractal dimension D of electrical trees approaches the fractal dimension of a percolation cluster when the fraction of conducting particles approximates the percolation limit.

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PubMed2000

Fractal analysis of electrical trees in a cross-linked synthetic resin.

A statistical picture of dielectric breakdown in cross-linked polyester resins for a two-dimensional geometry is presented and discussed in this paper. A connection is established between the dielectric breakdown model (DBM) and the physical properties of the resin. Distribution propagation times of simulated trees obey a Weibull statistics, as was experimentally found. This adjustment is achieved by a redefinition of the unit of time, which is different from the one employed up to date. The experimental dependence of characteristic propagation times on the fractal dimension D can be reproduced in the range 1.2<D<1.5. A relationship is established between the glass transition temperature T(g) and the DBM parameter eta, which is in agreement with thermodynamical considerations. It is suggested that fractal characteristics of electrical trees should be related to a basic material property, such as the cross-linking density, which implies a notion of universality that deserves to be explored.

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PubMed1999

Theoretical model of diatomic molecules interacting on a two-dimensional lattice.

The coverage-dependent binding energy of interacting dimers is investigated using the lattice gas model. Dimers with distinguishable ends are assumed to interact if they occupy only nearest-neighbor lattice sites. The interaction energy between a pair of dimers will be repulsive if identical ends are in nearest-neighbor positions and attractive if they are not. The grand partition function is derived by using the Bethe approximation. The energy of the system of interacting dimers is evaluated as a function of the lattice coverage at different temperatures and pair interaction potentials. Under the same conditions the average number of all types of nearest-neighbors is evaluated.

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