Biomedical subjects

E M Terentjev

Publications and source records attributed to E M Terentjev.

28 records · Page 2Linked to original sources

PubMed2002

UV manipulation of order and macroscopic shape in nematic elastomers.

A range of monodomain nematic liquid-crystal elastomers containing differing proportions of photoisomerizable mesogenic moieties, which turn from a rodlike to a kinked shape upon ultraviolet (uv) irradiation, was studied. Depending on the proportion and positional role of the photosensitive groups in the crosslinked polymer network, different types and magnitudes of response were found. The principle consequence of such photoisomerization is the destabilization of the nematic phase, whose order parameter depends on temperature in a near-critical fashion. Accordingly, the effect of uv irradiation is dramatically enhanced near the critical temperature, with the associated reduction in the nematic order parameter manifesting as a change in the macroscopic shape of the elastomer samples, producing a large uniaxial contraction. Theoretical analysis of this phenomenon gives a good quantitative agreement with experiment.

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PubMed2002

Effect of cross-linker geometry on dynamic mechanical properties of nematic elastomers.

We study three monodomain (single-crystal) nematic elastomer materials, all side-chain siloxane polymers with the same mesogenic groups but with different types of cross linking: (i) short flexible siloxane linkage affine to the network backbone, (ii) short flexible aliphatic cross links miscible with mesogenic side-chain groups, and (iii) long segments of main-chain nematic polymer. The dynamic mechanical response of these three systems shows a characteristically universal decrease of storage modulus and a corresponding increase of loss factor. This effect of "dynamic soft elasticity" is strongly anisotropic, depending on the nematic director orientation. We examine the important role of the average backbone chain anisotropy r(T)=l(parallel)/l(perpendicular), which is affected by the cross-linking geometry and contributes to the magnitude and frequency dependence of the dynamic anomaly, and discuss possible applications in mechanical damping and polarized acoustic technology.

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PubMed2002

Networks of helix-forming polymers.

Biological molecules can form hydrogen bonds between nearby residues, leading to helical secondary structures. The associated reduction of configurational entropy leads to a temperature dependence of this effect: the helix-coil transition. Since the formation of helices implies a dramatic shortening of the polymer dimensions, an externally imposed end-to-end distance R affects the equilibrium helical fraction of the polymer and the resulting force-extension curves show anomalous plateau regimes. In this article, we investigate the behaviour of a crosslinked network of such helicogenic molecules, particularly focusing on the coupling of the (average) helical content present in a network to the externally imposed strain. We show that both elongation and compression can lead to an increase in helical domains under appropriate conditions.

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PubMed2002

UV isomerisation in nematic elastomers as a route to photo-mechanical transducer.

The macroscopic shape of liquid-crystalline elastomers strongly depends on the order parameter of the mesogenic groups. This order can be manipulated if photo-isomerisable groups, e.g. containing N=N bonds, are introduced into the material. We have explored the large photo-mechanical response of such an azobenzene-containing nematic elastomer at different temperatures, using force and optical birefringence measurements, and focusing on fundamental aspects of population dynamics and the related speed and repeatability of the response. The characteristic time of "on" and "off" regimes strongly depends on temperature, but is generally found to be very long. We were able to verify that the macroscopic relaxation of the elastomer is determined by the nematic order dynamics and not, for instance, by the polymer network relaxation.

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PubMed2001

Effect of crosslinker geometry on equilibrium thermal and mechanical properties of nematic elastomers.

We study three monodomain (single-crystal) nematic elastomer materials, all side-chain siloxane polymers with the same mesogenic groups but with different types of crosslinking: (i) short flexible siloxane linkage affine to the network backbone, (ii) short flexible aliphatic crosslinks miscible with mesogenic side chain groups, and (iii) long segments of main-chain nematic polymer. Equilibrium physical properties of these three systems are very different, especially the spontaneous thermal expansion and anisotropic stress-strain response along and perpendicular to the uniform nematic director. In the latter case, we examine the soft elastic plateau during the director reorientation. We compare the nematic order-parameter Q(T), provided primarily by the side mesogenic groups and relatively constant between the samples, and the average backbone chain anisotropy r(T)=l( parallel)/l( perpendicular), which is strongly affected by the crosslinking geometry. The experimental data is compared quantitatively with theoretical models of nematic elastomers.

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PubMed2001

Cholesteric elastomers: deformable photonic solids.

A mechanical strain applied to a monodomain cholesteric elastomer modulates and eventually unwinds the helical director distribution. There are similarities with the classical problem of an electric field applied to a cholesteric liquid crystal, but also differences. Frank elasticity is of minor importance unless the gel is very weak. The interplay is rather between the director being helically anchored to the rubber elastic matrix and the external mechanical field. Stretching perpendicular to the helix axis induces the uniform unwound state via the elimination of sharp, pinned twist walls above a critical strain. Below the critical strain the coarsening of the director distribution is not accompanied by an increase but rather by an affine decrease in the pitch. Unwinding through conical director states occurs when the elastomer is stretched along the helical axis. Finally we consider cholesteric elastomers in a classical device geometry with an electric field applied along the pitch axis and hence transverse to the director orientation.

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PubMed2001

Anomalous viscoelastic response of nematic elastomers.

We report a combined theoretical and experimental study of linear viscoelastic response in oriented monodomain nematic elastomers. The model predicts a dramatic decrease in the dynamic modulus in certain deformation geometries in an elastic medium with an independently mobile internal degree of freedom, the nematic director with its own relaxation dynamics. Dynamic mechanical measurements on monodomain nematic elastomers confirm our predictions of dependence on shear geometry and on nematic order, and also show a very substantial mechanical loss clearly associated with director relaxation.

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PubMed2001

Topographic contrast of partially wetting water droplets in environmental scanning electron microscopy.

Partially wetting water droplets with sizes smaller than the capillary length acquire a distinct spherical cap shape controlled by the equilibrium contact angle, which is specific for different substrates and conditions. Images of such droplets in an environmental scanning electron microscope (ESEM) show strong topographic contrast. This contrast across the droplets can be analysed within a simple theoretical model, as the droplet sides are inclined smooth surfaces. Very small droplets have ESEM intensity profiles which deviate from this topographic model. Such deviations indicate that other sources of electron signal may be important for such droplets, and also demonstrate the limits of the analytical model. For droplets sufficiently large that they lie within the range of the topographic contrast model, values of contact angles on different substrates can be deduced. These are found to agree with independent direct measurements, as well as the results given in the literature. The possibilities of using this technique to analyse physical properties of different substrates are discussed.

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PubMed1999

Polydomain-monodomain transition in nematic elastomers.

Director textures and alignment of polydomain nematic elastomers under uniaxial extension are described theoretically applying the concept of randomly quenched disorder introduced by network cross-links. Within this model, treated with the replica trick and Gaussian variational approximation, the polydomain-monodomain transition occurs in a critical fashion with a small jump and rapid increase of the macroscopic order parameter. The transition is characterized by a plateau on the stress-strain curve. The critical stress value at which the transition takes place is estimated as approximately muQ(ch) with mu the rubber modulus of the elastomer and Q(ch) the parameter of chain anisotropy. The aligning of polydomain texture occurs via rotation of domains rather than their growth, with domain size almost unchanged through and above the transition. Experimental data obtained by several groups for various nematic elastomers are analyzed, showing a qualitative agreement with model predictions.

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PubMed1999

Electromechanical Fredericks effects in nematic gels.

The solid nematic equivalent of the Fredericks transition is found to depend on a critical field rather than a critical voltage as in the classical case. This arises because director anchoring is principally to the solid rubbery matrix of the nematic gel rather than to the sample surfaces. Moreover, above the threshold field, we find a competition between quartic (soft) and conventional harmonic elasticity which dictates the director response. By including a small degree of initial director misorientation, the calculated field variation of optical anisotropy agrees well with the conoscopy measurements of Chang et al. [Phys. Rev. E 56, 595 (1997)] of the electro-optical response of nematic gels.

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