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E V Veitsman

Publications and source records attributed to E V Veitsman.

5 recordsLinked to original sources

The interconnection between the surface tension and fluctuations within fine drops, bubbles, and their nuclei.

We consider the effect of surface tension upon fluctuations within the core of drops and bubbles. We also investigate the fluctuations of the substance density rho, volume V, and particle number N within the objects under study. It is demonstrated that cores of drops and bubbles are homogeneous when they contain several thousand nanoparticles (molecules, atoms). Fluctuations of particle number are very large within the nucleus core containing only a few nanoparticles. Therefore, the surface tension has a probabilistic character since there is no surface separating the nucleus substance from the surrounding medium, only a transitional zone whose radius fluctuates considerably in time. In this case, it is more correct to consider not the surface tension but a certain quantity that we named the quasi surface tension.

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On the rate of relativistic surface chemical reactions.

On the basis of special relativity and the classical theory of chemical reaction rates it is shown how the surface chemical reaction rates vary as v --> c, where v is the velocity of the object under study and c is the velocity of light.

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On relativistic surface tension.

On the basis of special relativity and classical thermodynamics, the surface tension was shown to be a relativistic invariant.

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Some problems of interface chemical mechanics.

On the basis of quasiton theory an expression was obtained for the potential of interpartical attractive macroforces in a curved interface, being between liquid and gas, for a centrally symmetric case when thickness the DeltaL of the area under study is commensurable with the radius of curvature r(s) of a bubble or a drop. Expressions were also obtained for normal and tangential components of a stress tensor in the interface; using variational principles, it is shown that density profiles in the interface cannot be equilibrium, and there is a probability that the surface tension for the fine bubble or drop may be even negative.

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