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Emil Mittag

Publications and source records attributed to Emil Mittag.

2 recordsLinked to original sources

Time-dependent fluctuation theorem.

The fluctuation theorem (FT) is a generalization of the second law of thermodynamics that applies to small systems observed for short times. For thermostated systems it gives the probability ratio that entropy will be consumed rather than produced. In the present paper, we propose a version of the FT that applies to thermostated dissipative systems which respond to time-dependent dissipative fields. In testing the time-dependent fluctuation theorem we provide convincing evidence that sets of trajectories with conjugate values for the time-integrated entropy production, (+/-A+/-deltaA), are indeed (for time-reversible dynamical systems such as those studied here), time-reversal images of one another. This observation verifies the deep connection between time-reversal symmetry, the fluctuation theorem, and the second law of thermodynamics.

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Experimental demonstration of violations of the second law of thermodynamics for small systems and short time scales.

We experimentally demonstrate the fluctuation theorem, which predicts appreciable and measurable violations of the second law of thermodynamics for small systems over short time scales, by following the trajectory of a colloidal particle captured in an optical trap that is translated relative to surrounding water molecules. From each particle trajectory, we calculate the entropy production/consumption over the duration of the trajectory and determine the fraction of second law-defying trajectories. Our results show entropy consumption can occur over colloidal length and time scales.

Journal Article↗