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F Bley

Publications and source records attributed to F Bley.

3 recordsLinked to original sources

X-ray diffraction from rectangular slits.

It is shown that for micrometre-sized beams the X-ray diffraction from slits is a source of strong parasitic background, even for slits of high quality. In order to illustrate this effect, the coherent diffraction from rectangular slits has been studied in detail. A large number of interference fringes with strong visibility have been observed using a single set of slits made of polished cylinders. For very small apertures, asymmetrical slits generate asymmetrical patterns. This pattern is calculated from the theory of electromagnetic field propagation and compared with experiment in the far-field regime. The use of guard slits to remove Fraunhofer diffraction from the beam-defining slits is treated theoretically. Numerical simulations yield the optimum aperture of the guard slits with respect to the distance to the primary slits. Diffraction theory is shown to be essential to understand how to reduce the background-to-signal ratio in high-resolution experiments.

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Kinetic evolution of unmixing in an AlLi alloy using x-ray intensity fluctuation spectroscopy.

Irreversible decomposition of an AlLi single crystal has been studied by x-ray photon correlation spectroscopy. The precipitate coarsening follows a universal behavior, as measured by the time-resolved average scattering. Using coherent scattering, two-time correlation functions have been measured. The time evolution of the speckle pattern gives new insight into the process of unmixing; at least two regimes govern this evaporation-condensation coarsening process. One is related to the overall arrangement of precipitates, and the characteristic time is linear with annealing time. The other is related to the motion of interfaces and is related to Porod's law.

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Aging in a filled polymer: coherent small angle x-ray and light scattering

Measurements are described using small angle coherent x-ray scattering and small angle dynamic light scattering of motion in fumed silica aggregates suspended in a poly(dimethyl siloxane) melt. At rest, this system develops weakly bound superstructures that are disrupted by mechanical stirring or thermal treatment. The observed relaxation rates correspond to a combination of liquidlike diffusion and a structural relaxation (flocculation) whereby the diffusing silica aggregates recombine into larger agglomerates at long times. Both processes are diffusion controlled. Two samples are investigated. The first, in which the silica is hydrophilic, is a highly viscous liquid for which the respective rate coefficients are about 5x10(-14) cm(2) s(-1) and 2x10(-15) cm(2) s(-1). The second sample, in which the silica surface is hydrophobic, is a thixotropic paste. The same aging mechanism in the diffusion is also observed, but with much slower rate constants, 2x10(-15) cm(2) s(-1) and 9x10(-16) cm(2) s(-1), respectively.

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