Selected patented cross-coupling reaction technologies.
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Catalysis↗
Biomedical subjects
Gérard Mignani
Publications and source records attributed to Gérard Mignani.
Second generation N-heterocyclic carbene-Pt(0) complexes as efficient catalysts for the hydrosilylation of alkenes.
A new class of benzimidazolylidene carbene-Pt(0) complexes was developed and used to efficiently catalyse the hydrosilylation of alkenes.
Journal Article↗
Modified BINAP: the how and the why.
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Journal Article↗
Selective and efficient platinum(0)-carbene complexes as hydrosilylation catalysts.
The hydrosilylation reaction enables the production of silicon polymers. Platinum-carbene complexes are reported that catalyze the hydrosilylation reaction of alkenes with remarkable efficiency and exquisite selectivity and avoid the formation of platinum colloids. By-products, typically encountered with previous catalytic systems, are suppressed with these platinum derivatives.
Journal Article↗
Platinum oxide (PtO(2)): a potent hydrosilylation catalyst.
[reaction: see text] Platinum oxide was found to be a versatile and powerful hydrosilylation catalyst upon a wide variety of functionalized alkenes and especially aminated alkenes. Moreover, highly reproducible results and easy removal make this new catalyst a useful tool for hydrosilylation reaction.
Journal Article↗