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GR Morrison

Publications and source records attributed to GR Morrison.

2 recordsLinked to original sources

Incoherent imaging with the soft X-ray microscope

The imaging characteristics for X-ray wavelengths in the "water window" under incoherent imaging conditions (large detector aperture) are examined for the King's College London scanning transmission X-ray microscope with zone-plate objective installed at the Daresbury (UK) synchrotron. The principal consideration was to express image theory, incorporating wave aberrations and apodised zone plates, and to apply the theory to experimental data. Comparisons are made, showing reasonable agreement, for a range of defocus values and two wavelengths. Due to problems in fabrication it was necessary to determine the effective, or operational, zone-plate parameters (radius of outermost active zone rN, width of outermost active zone drN); this was accomplished by through-focus series. Calculated point spread functions were used to deblurr images, in through-focus series of two-dimensional scanned X-ray images of specimen holes and test grating patterns. Significant contrast enhancement is achieved after deconvolution with a best point-to-point resolution of about 35 nm.

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Scanning Transmission X-Ray Microscopy: A New Method for the Investigation of Aggregation in Silica

During the preparation of silica by acidification of water glass, primary silica particles form extended and ramified aggregates. The growing aggregates form a gel, a tenuous network of interconnected aggregates. After aging and drying of the wet gel, porous silica is obtained. To study the extremely vulnerable aggregates only noninvasive methods are allowed. Moreover, because of the colloidal scale many methods based on (atomic or molecular scale) spectroscopy are not informative. Scanning transmission x-ray microscopy (STXM), using high-brilliance synchrotron radiation at 3.25 nm (380 eV) and 2.60 nm (480 eV) as an X-ray source, provides a new technique to obtain direct images of wet or solved aggregates at a 50-5000 nm scale. The 50 nm resolution is sufficient to provide excellent images of fractal structures. In this paper the principles of STXM are discussed in relation to investigations of wet gel systems like silica gel.

Journal Article↗