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Gunnar A Niklasson

Publications and source records attributed to Gunnar A Niklasson.

2 recordsLinked to original sources

New probe of the electronic structure of amorphous materials.

Here we show that electrochemical equilibrium voltage curves of amorphous WO3 and TiO2 coatings exhibit fine structure in striking agreement with the density of states in the conduction bands, as obtained by ab initio calculations for the crystalline counterparts. We suggest that localization of the band states is essential for observing the electronic structure. Our highly sensitive electrochemical method opens new vistas for studying the electronic structure of nonmetallic disordered materials that can be intercalated with an ionic species.

Journal Article↗

Coupled multipolar interactions in small-particle metallic clusters.

We propose a new formalism for computing the optical properties of small clusters of particles. It is a generalization of the coupled dipole-dipole particle-interaction model and allows one in principle to take into account all multipolar interactions in the long-wavelength limit. The method is illustrated by computations of the optical properties of N = 6 particle clusters for different multipolar approximations. We examine the effect of separation between particles and compare the optical spectra with the discrete-dipole approximation and the generalized Mie theory.

Journal Article↗