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H J Prosser

Publications and source records attributed to H J Prosser.

32 records · Page 2Linked to original sources

Zinc oxide eugenol cements. VI. Effect of zinc oxide type on the setting reactions.

The particle size and adsorbed water on zinc oxide from various sources have been investigated and related to the reactivity with eugenol. The reactivity of zinc oxide with eugenol alone increases with the amount of water reversibly adsorbed. When 1% acetic acid is added to eugenol, the reactivity increases as the particle size of the oxide decreases. Generally, zinc oxide powders are deactivated by heat treatment because of coalescence of particles and loss of the ability to readsorb water.

Adsorption↗

Infrared spectroscopic studies on the development of crystallinity in dental zinc phosphate cements.

An infrared spectroscopic study has been made of the development of crystallinity (hopeite) in dental zinc phosphate cements. Crystallization in the bulk of a cement is prevented only by the incorporation, in the liquid, of aluminum which forms complexes with phosphoric acid. The development of surface crystallinity is related to the chemical composition of the cement and the speed of the reaction. No acid phosphates are to be found in the matrix which consists solely of neutral orthophosphates.

Aluminum↗

Comparison of the nuclear magnetic resonance and infrared spectroscopic methods for the quantitative analysis of polydimethylsiloxane.

A method based on nuclear magnetic resonance spectroscopy is described for the quantitative determination of polyimethylsiloxane (PMS) in a variety of pharmaceutical preparations. An extraction procedure using deuterochloroform within the sample tube was devised. In the presence of an internal standard, the PMS concentration was determined directly using integrated peak areas, without the necessity of establishing calibration curves. Accurate quantitative results were achieved with sample, containing at least 2mg PMS, extracted from formulations containing greater than 0.5% PMS. The extraction procedure and nmr assay were both more efficient and convenient than the B.P.C. method.

Chloroform↗