Interactions and two-phase coexistence in nonionic micellar solutions as determined by static light scattering.
We suggest semi-phenomenological approaches for the pair interaction potential in aqueous C(m)E(n) solutions. These expressions are non-linear least squares fitted to static light scattering data from solutions of C(m)E4 and C(m)E8 surfactants in the long wavelength limit. From the resulting interaction parameters we calculate the location of the liquid/liquid two phase coexistence curves, which are in very good agreement with experimental data reported by others.
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