Biomedical subjects

Heino Finkelmann

Publications and source records attributed to Heino Finkelmann.

6 recordsLinked to original sources

PubMed2006

Phase biaxiality in nematic liquid crystalline side-chain polymers of various chemical constitutions.

In a previous deuterium NMR study conducted on a liquid crystalline (LC) polymer with laterally attached book-shaped molecules as the mesogenic moiety, we have revealed a biaxial nematic phase below the conventional uniaxial nematic phase (Phys. Rev. Lett. 2004, 92, 125501). To elucidate details of its formation, we here report on deuterium NMR experiments that have been conducted on different types of LC side-chain polymers as well as on mixtures with low-molar-mass mesogens. Different parameters that affect the formation of a biaxial nematic phase, such as the geometry of the attachment, the spacer length between the polymer backbone and the mesogenic unit, as well as the polymer dynamics, were investigated. Surprisingly, also polymers with terminally attached mesogens (end-on polymers) are capable of forming biaxial nematic phases if the flexible spacer is short and thus retains a coupling between the polymer backbone and the LC phase. Furthermore, the most important parameter for the formation of a biaxial nematic phase is the dynamics of the polymer backbone, as the addition of a small percentage of low molar mass LC to the biaxial nematic polymer from the original study served to shift both the glass transition and the appearance of detectable biaxiality in a very similar fashion. Plotting different parameters for the investigated systems as a function of T/Tg also reveals the crucial role of the dynamics of the polymer backbone and hence the glass transition.

Crystallization↗

PubMed2005

Low-voltage-driven electromechanical effects of swollen liquid-crystal elastomers.

We experimentally investigate, in detail, electromechanical effects in liquid-crystal elastomers (LCEs) previously swollen with low-molecular-weight liquid crystals (LMWLCs). Both polydomain (POLY) and monodomain (MONO) LCEs were studied. We used a well known LMWLC, 4-n-pentyl-4-cyanobiphenyl (5CB) as a solvent. After swelling POLY and MONO LCEs (LSCE) with 5CB, shape changes were measured by recording the displacement of the edge of the swollen LCE at different voltages, V, and temperature. With 100 microm distance between electrodes, measurable shape changes (approximately 1-20 microm) are observed with small voltages (V approximately 0.5-10 V). In particular, we note that, compared to unswollen L(S)CEs, a dramatic approximately 200 times decrease of the threshold field was found for electromechanical effects in swollen L(S)CEs. While swollen MONO LCEs showed electromechanical effects in the planar geometry, homeotropic MONO swollen with homeotropically oriented 5CB did not. This is easy to understand because, in the homeotropic case, the liquid-crystal preferred axis is already aligned with the field so the field has no reorienting effect. The inverse of the response time when the field was switched on in both POLY and MONO was proportional to E2, which is the same field dependence as the response time of LMWLCs. When the field was switched off, the relaxation time showed a field dependence different from that of LMWLCs that we attribute to relaxation of the LCE network.

Journal Article↗

PubMed2004

Disorder by random crosslinking in smectic elastomers.

We present a high-resolution x-ray study of the effects of disorder due to random crosslinking on the one-dimensional translational ordering in smectic elastomers. At a small crosslink density of about 5%, the elastomer network stabilizes the smectic structure against layer-displacement fluctuations, and the algebraically decaying layer ordering extends up to several micrometers. With increasing concentration of crosslinks, the finite size of these domains is strongly reduced, indicating that disordering takes over. Finally, at a crosslink concentration of 20%, the structure factor can be described by a Lorentzian, which signals extended short-range correlations. The findings are discussed in terms of recent theories of randomly quenched disorder.

Journal Article↗

PubMed2004

Fast liquid-crystal elastomer swims into the dark.

Liquid-crystal elastomers (LCEs) are rubbers whose constituent molecules are orientationally ordered. Their salient feature is strong coupling between the orientational order and mechanical strain. For example, changing the orientational order gives rise to internal stresses, which lead to strains and change the shape of a sample. Orientational order can be affected by changes in externally applied stimuli such as light. We demonstrate here that by dissolving-rather than covalently bonding-azo dyes into an LCE sample, its mechanical deformation in response to non-uniform illumination by visible light becomes very large (more than 60 degrees bending) and is more than two orders of magnitude faster than previously reported. Rapid light-induced deformations allow LCEs to interact with their environment in new and unexpected ways. When light from above is shone on a dye-doped LCE sample floating on water, the LCE 'swims' away from the light, with an action resembling that of flatfish such as skates or rays. We analyse the propulsion mechanism in terms of momentum transfer.

Azo Compounds↗

PubMed2004

Swelling dynamics of liquid crystal elastomers swollen with low molecular weight liquid crystals.

We experimentally investigated the swelling behavior of thin films (approximately 150 microm) of liquid crystalline elastomers (LCEs) by low molecular weight liquid crystals (LMWLCs). The two LMWLCs used are the well-known nematic liquid crystals, 4-n-pentyl-4-cyanobiphenyl, and 4-methoxy-benzilidene-4-butyl-aniline. Both polydomain (POLY) and monodomain (MONO) LCE swelling are studied. In MONO LCEs (LSCEs), the director n empty set is uniformly oriented throughout the film. POLY films are made of many domains with different orientations. Its swelling behavior was similar to isotropic gels. In contrast, LSCEs revealed interesting results not anticipated by any theory. First, the LMWLC enters the LSCE by front propagation about three-times faster axially n empty set than radially n empty set. Second, only the LSCE dimensions radially n empty set expanded, while that axially n empty set did not change at all. Third, when the LMWLC director and the LSCE director are aligned (MONO2 samples), swelling takes place about twice as fast as when they are not aligned. Volume change dynamics of swollen L(S)CEs investigated as a function of temperature revealed several phase transitions by optical and calorimetry techniques.

Journal Article↗

PubMed2003

Defect mode emission of a dye doped cholesteric polymer network.

We have observed enhanced fluorescence and laser emission due to a photonic defect mode in a dye doped cholesteric polymer network. The defect is caused by a phase jump of the cholesteric helix at the interface of two stacked layers of a cholesteric polymer film. Fluorescence spectra show an additional resonant mode inside the photonic stop band. Pulsed excitation gives rise to laser emission of the defect mode, with an exceptionally low lasing threshold. The defect mode emission has a circular polarization whose sense of rotation is opposite to that of the cholesteric helix.

Journal Article↗