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Biomedical subjects

Ingo Fischer

Publications and source records attributed to Ingo Fischer.

11 recordsLinked to original sources

Zero-lag long-range synchronization via dynamical relaying.

We show that isochronous synchronization between two delay-coupled oscillators can be achieved by relaying the dynamics via a third mediating element, which surprisingly lags behind the synchronized outer elements. The zero-lag synchronization thus obtained is robust over a considerable parameter range. We substantiate our claims with experimental and numerical evidence of such synchronization solutions in a chain of three coupled semiconductor lasers with long interelement coupling delays. The generality of the mechanism is validated in a neuronal model with the same coupling architecture. Thus, our results show that zero-lag synchronized chaotic dynamical states can occur over long distances through relaying, without restriction by the amount of delay.

Journal Article↗

Excited mixed-valence states of symmetrical donor-acceptor-donor pi systems.

We investigated the spectroscopic properties of a series of four bistriarylamine donor-pi-bridge-donor D-pi-D compounds (dimers), composed of two asymmetric triarylamine chromophores (monomers). UV/vis, fluorescence, and transient absorption spectra were recorded and compared with those of the corresponding D-pi monomers. Bilinear Lippert-Mataga plots indicate a major molecular reorganization of the excited state in polar media for all compounds. The excited states of the dimers are described as mixed-valence states that show, depending on the chemical nature of the pi bridge, a varying amount of interactions (couplings). We found that superradiant emission, that is, an enhancement of the fluorescence rate in the dimer, is observed only in the case of weak and medium coupling. Whether the first excited-state potential energy surface of the dimers is described by single minimum or a double minimum potential depends on the solvent polarity and the electronic coupling. In the latter case, the dimer relaxes in a symmetry broken CT state with partial positive charge at the triarylamine donor and negative charge at the pi bridge. The [2.2]paracyclophane bridged dimer is an example of a weakly coupled system because the spectroscopic behavior is very similar to the corresponding p-xylene monomer. In contrast, anthracene as well as p-xylene bridges mediate a stronger coupling and reveal a significant cooperative influence on the optical properties.

Journal Article↗

Photodissociation of thymine.

We discuss the photochemistry and photodissociation dynamics of thymine as revealed by two-colour photofragment Doppler spectroscopy and by one-colour slice imaging. Thymine is optically excited into the pipi* state, known to deactivate quickly. The H atom photofragment spectra are dominated by two-photon excitation processes with subsequent statistical dissociation. This can be explained by absorption of a second photon from a long-lived dark state to a highly excited state that quickly deactivates to the electronic ground state. No evidence was found for an important role of the pisigma* excited state identified in adenine and many other heterocyclic molecules.

Algorithms↗

Episodic synchronization via dynamic injection.

We report the occurrence of spontaneous synchronizing events between two semiconductor lasers, when the emission of a frequency- and intensity-chaotic driving laser is unidirectionally coupled into a second stable response laser. The driving laser is driven chaotic by delayed optical feedback, the response laser is a device-identical solitary laser. We demonstrate the onset of an episodic synchronization regime when the two lasers are spectrally detuned with respect to each other. By a joint experimental and modeling analysis we can attribute the onset and the duration of the episodes to properties of spectral overlap of both lasers. This effect can even give rise to seemingly anticorrelated intensity behavior. We expect episodic synchronization to be a generic scenario for the loss of synchronization of chaotic oscillators exhibiting frequency cycles.

Journal Article↗

Chaos-based communications at high bit rates using commercial fibre-optic links.

Chaotic signals have been proposed as broadband information carriers with the potential of providing a high level of robustness and privacy in data transmission. Laboratory demonstrations of chaos-based optical communications have already shown the potential of this technology, but a field experiment using commercial optical networks has not been undertaken so far. Here we demonstrate high-speed long-distance communication based on chaos synchronization over a commercial fibre-optic channel. An optical carrier wave generated by a chaotic laser is used to encode a message for transmission over 120 km of optical fibre in the metropolitan area network of Athens, Greece. The message is decoded using an appropriate second laser which, by synchronizing with the chaotic carrier, allows for the separation of the carrier and the message. Transmission rates in the gigabit per second range are achieved, with corresponding bit-error rates below 10(-7). The system uses matched pairs of semiconductor lasers as chaotic emitters and receivers, and off-the-shelf fibre-optic telecommunication components. Our results show that information can be transmitted at high bit rates using deterministic chaos in a manner that is robust to perturbations and channel disturbances unavoidable under real-world conditions.

Journal Article↗

Competition between van der Waals and hydrogen bonding interactions: structure of the trans-1-naphthol/N(2) cluster.

The excitation energy in the multiphoton ionization spectrum of the trans-1-naphthol/N(2) cluster shows only a small red shift with respect to isolated naphthol, indicating a van der Waals pi-bound structure rather than a hydrogen-bonded one. To confirm this interpretation, high-level electronic structure calculations were performed for several pi- and hydrogen-bonded isomers of this cluster. The calculations were carried out at the second order Møller-Plesset (MP2) level of perturbation theory with the family of correlation consistent basis sets up to quintuple-zeta quality including corrections for the basis set superposition error and extrapolation to the MP2 complete basis set (CBS) limit. We report the optimal geometries, vibrational frequencies, and binding energies (D(e)), also corrected for harmonic zero-point energies (D(0)), for three energetically low-lying isomers. In all calculations the lowest energy structure was found to be an isomer with the N(2) molecule bound to the pi-system of the naphthol ring carrying the OH group. In the CBS limit its dissociation energy was computed to be D(0) = 2.67 kcal/mol (934 cm(-1)) as compared to D(0) = 1.28 kcal/mol (448 cm(-1)) for the H-bound structure. The electronic structure calculations therefore confirm the assignment of the experimental electronic spectrum corresponding to a van der Waals pi-bound structure. The energetic stabilization of the pi-bound isomer with respect to the hydrogen-bonded one is rather unexpected when compared with previous findings in related systems, in particular phenol/N(2).

Computer Simulation↗

Wave chaos in real-world vertical-cavity surface-emitting lasers.

We report the onset of wave chaos in a real-world vertical-cavity surface-emitting laser. In a joint experimental and modeling approach we demonstrate that a small deformation in one layer of the complicated laser structure changes the emission properties qualitatively. Based on the analysis of the spatial emission profiles and spectral eigenvalue spacing distributions, we attribute these changes to the transition from regular behavior to wave chaos, and justify the full analogy to two-dimensional billiards by model calculations. Hence, these lasers represent fascinating devices for wave chaos studies.

Journal Article↗

Excited-state decay of hydrocarbon radicals, investigated by femtosecond time-resolved photoionization: ethyl, propargyl, and benzyl.

The excited state decay of the hydrocarbon radicals ethyl, C(2)H(5); propargyl, C(3)H(3); and benzyl, C(7)H(7) was investigated by femtosecond time-resolved photoionization. Radicals were generated by flash pyrolysis of n-propyl nitrite, propargyl bromide, and toluene, respectively. It is shown that the 2 (2)A(') (3s) Rydberg state of ethyl excited at 250 nm decays with a time constant of 20 fs. No residual signal was observed at longer delay times. For the 3 (2)B(1) state of propargyl excited at 255 nm a slower decay with a time constant 50+/-10 fs was determined. The 4 (2)B(2) state of benzyl excited at 255 nm decays within 150+/-30 fs.

Journal Article↗

Control of the spatiotemporal emission of a broad-area semiconductor laser by spatially filtered feedback.

We demonstrate the control of the spatiotemporal emission dynamics of a broad-area semiconductor laser in an external optical feedback configuration formed by a spatially filtering mirror. The emission properties are studied with a single-shot streak camera with temporal resolution of approximately 7 ps and spatial resolution of approximately 5 microm. Our results show a significant reduction of the spatial filamentation and, furthermore, suppression of the spatiotemporal instabilities, which are both intrinsic emission properties of standard high-power broad-area lasers. Associated with the control of the emission dynamics, strong improvement of the beam quality, which is essential for numerous high-power applications, is possible.

Journal Article↗

Time-resolved photoionisation of radicals, clusters and biomolecules: relevant model systems.

Laser spectroscopy of isolated molecules is more and more driven by chemically relevant questions rather than toward technological development. In this paper, experiments on selected examples of chemically interesting systems will be reviewed, demonstrating the power of laser spectroscopy in molecular beams. We will discuss experiments on allyl (C3H5) and propargyl (C3H3) radicals as examples of the investigation of unimolecular reactions of hydrocarbon radicals, excited-state proton transfer in 1-naphthol/ammonia clusters as an example of acid-base reactions in hydrogen-bonded clusters, and the photophysics of adenine as an example of the spectroscopy of biological molecules. Time-resolved photoionisation and photoelectron spectroscopy is shown to be a particularly powerful method for unravelling the chemistry of these systems.

Adenine↗

Synchronization of chaotic semiconductor laser systems: a vectorial coupling-dependent scenario.

We demonstrate the influence of vectorial coupling on the synchronization behavior of complex systems. We study two semiconductor lasers subject to delayed optical feedback which are unidirectionally coherently coupled via their optical fields. Our experimental and numerical results demonstrate a characteristic synchronization scenario in dependence on the relative feedback phase leading cyclically from chaos synchronization to almost uncorrelated states, and back to chaos synchronization. Finally, we reveal the influence of the feedback phase on the dynamics of the solitary delay system.

Journal Article↗