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J Bould

Publications and source records attributed to J Bould.

6 recordsLinked to original sources
PubMed2001

The nido-osmaboranes [2,2,2-(CO)(PPh(3))(2)-nido-2-OsB(5)H(9)] and [6,6,6-(CO)(PPh(3))(2)-nido-6-OsB(9)H(13)].

The structural characterization of the osmahexaborane 2-carbonyl-2,2-bis(triphenylphosphine)-nido-2-osmahexaborane(9), [Os(B(5)H(9))(C(18)H(15)P)(2)(CO)], (I), a metallaborane analogue of B(6)H(10), confirms the structure proposed from NMR spectroscopy. The structure of the osmadecaborane 6-carbonyl-6,6-bis(triphenylphosphine)-nido-6-osmadecaborane(13), [Os(B(9)H(13))(C(18)H(15)P)(2)(CO)], (IV), is similarly confirmed. The short basal B-B distance of 1.652 (8) A in (I), not bridged by an H atom, mirrors that in the parent hexaborane(10) [1.626 (4) A].

Journal Article↗
PubMed2001

Ten-vertex rhodadithiaborane chemistry:.

Neutral 8-(5-iodo-n-pentyl)-3-(eta(5)-pentamethylcyclopentadienyl)-arachno-3-rhoda-7,8-dithiaundecaborane, [Rh(C(5)H(19)B(8)IS(2))(C(10)H(15))], obtained from the [arachno-7,8-S(2)B(9)H(10)](-) anion by treatment with I(CH(2))(5)I followed by [Rh(C(5)Me(5))Cl(2)](2) and N,N,N',N'-tetramethyl-1,8-diaminonaphthalene, has the 11-vertex cluster geometry of [arachno-7,8-S(2)B(9)H(10)](-), but with an [Rh(C(5)Me(5))] unit in the 3-position instead of a [BH] unit, and with a -(CH(2))(5)I chain attached exo to an S atom.

Journal Article↗
PubMed2001

Two iridanonaborane compounds.

Two iridanonaborane compounds, 4-carbonyl-5,6:8,9-bis-muH-4-hydrido-4-bis(trimethylphosphine)-4-irida-arachno-nonaborane(12), [IrH(B8H12)(C3H9P)2(CO)], (Ia), and 2-carbonyl-2,5:6,9:8,9-tri-muH-4-chloro-2-bis(trimethylphosphine)-2-irida-nido-nonaborane(11), [Ir(B8H10Cl)(C3H9P)2(CO)], (II), are described. Compound (II) shows evidence of effective chlorine-substituent migration during its formation.

Journal Article↗
PubMed2001

[Mu-6,9-Cl-8-(OMe)-6,9-eta5-C5Me5)2-arachno-6,9,5-rh2SB7H7].

The title compound, mu-6,9-chloro-8-methoxy-6,9-bis(eta5-pentamethylcyclopentadienyl)-6,9-dirhoda-5-thia-arachno-decaborane(7), [Rh2(CH10B7OS)(C10H15)2Cl], has a single Cl atom bridging the two remote rhodium 'prow' vertices of an arachno ten-vertex dirhodathiadecaborane cluster, with Rh-Cl distances of 2.3475 (11) and 2.3536 (11) A, and an Rh-Cl-Rh angle of 106.82 (4) degrees.

Journal Article↗
PubMed2000

[1,1,2,2-]

The title compound, 1,1,2,2-tetracarbonyl-1,2-&mgr;-carbonyl-4, 11-dimethylsulfido-closo-1,2-dicobaltadodecaborane, [Co(2)(C(4)H(20)B(10)S(2))(CO)(5)], has a closo 12-vertex 1, 2-Co(2)B(10)H(8) structure with SMe(2) ligands at the exo-4- and 11-positions. The cluster displays close structural similarities to the SEt(2) analogue.

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