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Biomedical subjects

J Calderon-Moreno

Publications and source records attributed to J Calderon-Moreno.

3 recordsLinked to original sources

Sonochemical deposition of Au nanoparticles on titania and the significant decrease in the melting point of gold.

In this article, sub-micron size particles of titania were coated by a nanosized gold particles with the aid of power ultrasound. We could achieve a uniform coating of gold nanoparticles on a titania surface with a maximum gold loading of 10 wt%. In addition, we report on the experimental evidence for a significant decrease in the melting point of gold nanoparticles (<2 nm) by approximately 850 degrees C from that of the bulk material.

Coated Materials, Biocompatible↗

Ultrasound-assisted polyol method for the preparation of SBA-15-supported ruthenium nanoparticles and the study of their catalytic activity on the partial oxidation of methane.

Metallic Ru nanoparticles have been successfully produced and incorporated into the pores of SBA-15 in situ employing a simple ultrasound-assisted polyol method. The product has been confirmed by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy, where ultrasound provides both the energy for the reduction of the Ru(III) ion and the driving force for the loading of the Ru(0) nanoparticles into the SBA-15 pores. An ultrasound-assisted insertion mechanism has been proposed based on the microjets and shake-wave effect of the collapsed bubbles. The catalytic properties of the SBA-15-supported Ru nanoparticles have been tested by the partial oxidization of methane and show very high activity and high CO selectivity.

Catalysis↗