Laser deposition of polymer and biomaterial films.
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Biomedical subjects
Publications and source records attributed to J S Horwitz.
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We have studied the transport properties of disordered WSi films near the metal/insulator transition (MIT) and we have also reviewed the data for several other disordered materials near their MIT. In all cases, we found the presence of enhanced superconductivity. We constructed a superconductivity "phase diagram" (i.e., T(c) versus sigma) for each system, which reveals a striking correlation: In all cases, T(c) values are significantly enhanced only for samples whose conductivities lie within a narrow range on the metallic side of, and moderately near, the MIT. We present a heuristic model to explain this phenomenon.
Nanosecond transient spectroscopic measurements of the BATHO products formed from photolysis of bovine rhodopsin (RHO) and isorhodopsin (ISO) are discussed. BATHO absorption spectra of RHO and ISO differ slightly, but both pigments exhibit wavelength maxima near 560 nm. An additional transient absorption at 440 nm is observed immediately following excitation of RHO but not ISO. The decay times and Arrhenius activation energies of the two 560 nm absorbing transients are the same. In addition to spectral differences in the photolysis of RHO and ISO, the bleaching yield as a function of 532 nm laser power is different, with the yield in RHO saturating at lower laser power than ISO. The bleaching yield of the two pigments has been modeled using the known extinction coefficients and quantum yields for the interconversion of RHO, ISO, and a single BATHO species. Agreement between experiment and the model is found if the effects of the laser polarization are considered. The data are consistent with a common BATHO in the photolysis of RHO and ISO.
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Explore the source record for details and available documents.
Explore the source record for details and available documents.