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Jürgen Rahmer

Publications and source records attributed to Jürgen Rahmer.

2 recordsLinked to original sources

Three-dimensional radial ultrashort echo-time imaging with T2 adapted sampling.

The application of 3D radial sampling of the free-induction decay to proton ultrashort echo-time (UTE) imaging is reported. The effects of T2 decay during signal acquisition on the 3D radial point-spread function are analyzed and compared to 2D radial and 1D sampling. It is found that in addition to the use of ultrashort TE, the proper choice of the acquisition-window duration TAQ is essential for imaging short-T2 components. For 3D radial sampling, a maximal signal-to-noise ratio (SNR) with negligible decay-induced loss in spatial resolution is obtained for an acquisition-window duration of TAQ approximately 0.69 T2. For 2D and 1D sampling, corresponding values are derived as well. Phantom measurements confirm the theoretical findings and demonstrate the impact of different acquisition-window durations on SNR and spatial resolution for a given T2 component. In vivo scans show the potential of 3D UTE imaging with T2-adapted sampling for musculoskeletal imaging using standard MR equipment. The visualization of complex anatomy is demonstrated by extracting curved slices from the isotropically resolved 3D UTE image data.

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W- and X-band EPR investigation of Sc3@C82.

Sc3@C82 has been investigated by X- and W-band EPR. The isotropic and anisotropic hyperfine interaction between the electron spin and the 45Sc nuclei of the Sc3-triangle was evaluated. In addition, a statistical model analyzing the 13C hyperfine coupling of the C82 cage is applied and its consequences for the charge transfer are discussed. The observed EPR line broadening with decreasing temperature was modeled with a simple exchange model, which considers the molecular motion of the Sc3-triangle inside the C82 cage. This allowed the estimation of the linewidth contributions of the hyperfine- and g-anisotropies as well as the temperature dependence of the exchange rate, which increases rapidly with temperature and follows an exponential law.

Journal Article↗