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Jan Zaanen

Publications and source records attributed to Jan Zaanen.

6 recordsLinked to original sources
PubMed2005

An intrinsic limit to quantum coherence due to spontaneous symmetry breaking.

We investigate the influence of spontaneous symmetry breaking on the decoherence of a many-particle quantum system. This decoherence process is analyzed in an exactly solvable model system that is known to be representative of symmetry broken macroscopic systems in equilibrium. It is shown that spontaneous symmetry breaking imposes a fundamental limit to the time that a system can stay quantum coherent. This universal time scale is t(spon) approximately = 2piNH/(kBT), given in terms of the number of microscopic degrees of freedom N, temperature T, and the constants of Planck (h) and Boltzmann (kB).

Journal Article↗
PubMed2005

Photo-CIDNP solid-state NMR on photosystems I and II:what makes P680 special?

The origin of the extraordinary high redox potential of P680, the primary electron donor of Photosystem II, is still unknown. Photochemically induced dynamic nuclear polarisation (photo-CIDNP) 13C magic-angle spinning (MAS) NMR is a powerful method to study primary electron donors. In order to reveal the electronic structure of P680, we compare new photo-CIDNP MAS NMR data of Photosystem II to those of Photosystem I. The comparison reveals that the electronic structure of the P680 radical cation is a Chl a cofactor with strong matrix interaction, while the radical cation of P700, the primary electron donor of Photosystem I, appears to be a Chl a cofactor which is essentially undisturbed. Possible forms of cofactor-matrix interactions are discussed.

Electron Transport↗