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Jean-Guy Demers

Publications and source records attributed to Jean-Guy Demers.

2 recordsLinked to original sources

Columnar phases of three-fold molecular structures.

We study the occurrence of both positional and helical orders, for three-fold symmetric flat molecules in a columnar liquid crystal phase D(hd). Working in the group-theoretical Landau's framework, we identify a set of three order parameters giving rise to supercells of intercalated column with helical order and opposite helicities, as observed experimentally. The first-order nature of the transition is also discussed. The degrees of freedom introduced give rise to various other phases, including a new type, having helical order but no positional order along the columns.

Journal Article↗

Transition to ordered intercalated columns in columnar liquid crystals.

A phenomenological description of the phase transition between the disordered columnar phase Dhd and the ordered phase Dho is presented in which the columns are ordered and displaced so as to relieve the intrinsic frustration on a triangular lattice. A number of additional phases are predicted, including the one observed experimentally for the hexa-hexylthiotriphenylene columnar liquid crystal.

Journal Article↗