PubMed Health⌕ Search

Biomedical subjects

Jianshe Huang

Publications and source records attributed to Jianshe Huang.

8 recordsLinked to original sources

Complete 1H and 13C NMR assignments of four new steroidal glycosides from a gorgonian coral Junceella juncea.

Four new cholest-type steroidal glycosides, junceellosides A-D, isolated from the EtOH/CH(2)Cl(2) extracts of the South China Sea gorgonian coral Junceella juncea, were identified. Complete assignments of the (1)H and (13)C NMR chemical shifts for these compounds were achieved by means of one- and two-dimensional NMR techniques, including (1)H-(1)H COSY, HSQC, HMBC and NOESY spectra.

Animals↗

Oleanane triterpenes from Aegiceras corniculatum.

A new oleanane triterpene, 16alpha-hydroxy-l3,28-epoxyoleanan-3-one 1, was isolated from the stem bark of Aegiceras corniculatum, together with protoprimulagenin, aegicerin, embelinone, syringic acid, gallic acid, isorhamnetin and isorhamnetin 3-O-alpha-L-rhamnofuranosyl-(1-->6)-beta-D-glucopyranoside. Their structures were determined by spectroscopic methods.

Humans↗

A new unsaturated glycoglycerolipid from a cultured marine dinoflagellate Amphidinium carterae.

From the cultured marine dinoflagellate Amphidinium carterae, a new unsaturated glycoglycerolipid (2S)-1,2-O-6,9,12,15-dioctadecatetraenoyl-3-O-[alpha-D-galactopyranosyl-(1''''-->6''')-O-beta-D-galactopyranosyl]-glycerol (1), has been isolated together with two known saturated ones, (2S)-1,2-distearoyl-3-O-(6-sulpho-alpha-D-quinovopyranosyl)-glycerol (2) and (2S)-1-stearoyl-3-O-(6-sulpho-alpha-D-quinovopyranosyl)-glycerol (3). Their structures were elucidated on the basis of chemical and spectral data.

Animals↗

Xyloccensins O and P, unique 8,9,30-phragmalin ortho esters from Xylocarpus granatum.

Two unique 8,9,30-phragmalin ortho esters, xyloccensins O (1) and P (2), were isolated from the mangrove plant Xylocarpus granatum. They are a new type of ortho ester of phragmalin. The structures were determined by spectroscopic and single-crystal X-ray diffraction techniques. The biogenetic pathway to these new phragmalins was also proposed. [structure: see text]

Crystallography, X-Ray↗

Complete assignments of 1H and 13C NMR data for 10 phenylethanoid glycosides.

Ten phenylethanoid glycosides, including two new ones, isolated from the aerial parts of the mangrove plant Acanthus ilicifolius were identified. The first complete assignments of the 1H and 13C NMR chemical shifts for these glycosides were achieved by means of 2D NMR techniques, including 1H-1H COSY, TOCSY, HSQC and HMBC spectra.

Acanthaceae↗

New aliphatic alcohol and (Z)-4-coumaric acid glycosides from Acanthus ilicifolius.

From the aerial parts of Acanthus ilicifolius, a new aliphatic alcohol glycoside (ilicifolioside C) and two new (Z)-4-coumaric acid glycosides, (Z)-4-coumaric acid 4-O-beta-D-glucopyranoside and (Z)-4-coumaric acid 4-O-beta-D-apiofuranosyl-(1"-->2')-O-beta-D-glucopyranoside were isolated. The structural elucidations were based on the analyses of spectroscopic data. Z-Form 4-coumaric acid glycosides were first isolated from plant.

Acanthaceae↗