Justin R Lawrence | PubMed Health

PubMed2004

Optical amplification in a first-generation dendritic organic semiconductor.

We report a study of a new class of organic semiconductor as an optical gain medium. We demonstrate amplification of violet light by use of stimulated emission in a solution of a first-generation bis-fluorene-cored semiconducting dendrimer. Amplification is also observed in the solid state by means of amplified spontaneous emission in an optically pumped dendrimer planar waveguide. Gains of 36 dB cm(-1) at 420 nm and 26 dB cm(-1) at 390 nm in solution and 350 dB cm(-1) in the solid state are obtained. These results show that semiconducting dendrimers have potential as visible laser and amplifier materials.

Journal Article↗

PubMed2002

Comparison of holographic photopolymer materials by use of analytic nonlocal diffusion models.

The one-dimensional diffusion equation governing holographic grating formation in photopolymers, which includes both nonlocal material response and generalized dependence of the rate of polymerization on the illuminating intensity, has been previously solved under the two-harmonic expansion assumption. The resulting analytic expressions for the monomer and polymer concentrations have been derived and their ranges of validity tested in comparison with the more accurate numerical four-harmonic case. We used these analytic expressions to carry out a study of experimental results presented in the literature over a 30-year period. Automatic fitting of the data with these formulas allows material parameters, including the nonlocal chain-length variance sigma, to be estimated. In this way, (i) a quantitative comparison of different materials can be made, and (ii) a standard form of experimental result presentation is proposed to facilitate such a procedure.

Journal Article↗