Biomedical subjects

K Braitenbach

Publications and source records attributed to K Braitenbach.

3 recordsLinked to original sources

PubMed2001

Doxylaminium tetrachlorocuprate(II).

The structure of the title compound, 2-[1-(dimethylammonioethoxy)-1-phenylethyl]pyridinium tetrachlorocuprate(II), (C(17)H(24)N(2)O)[CuCl(4)], contains dihydro cations of doxylamine hydrogen bonded to two Cl atoms in two different [CuCl(4)](2-) anions, with Cl...N distances of 3.101 (9) and 3.253 (10) A. The ethereal O atom is involved in intramolecular hydrogen bonds, with O.N distances of 2.517 (11) and 2.757 (12) A. The molecular dimensions in the cation are as expected and the [CuCl(4)](2-) anion has a flattened tetrahedral geometry.

Journal Article↗

PubMed2000

Clemizoledichlorocobalt(II).

The structure of dichloro[1-(p-chlorobenzyl)-2-(1-pyrrolidinylmethyl-N)-1, 3-benzimidazole-N(3)]cobalt(II), [CoCl(2)(C(19)H(20)ClN(3))], contains a molecule of clemizole bound in a bidentate manner to cobalt through its imidazole and pyrrolidinyl N atoms, with significantly different Co-N distances of 1.976 (5) and 2.126 (5) A, respectively. The geometry around cobalt is distorted tetrahedral, with significantly different Co-Cl distances of 2.217 (2) and 2.233 (2) A, and the pyrrolidinyl ring is disordered.

Benzimidazoles↗

PubMed2000

Astemizole tetrachlorocuprate(II).

The structure of ¿3-[(4-fluorophenyl)methyl]-1H-benzimidazol-2-ylidene¿¿1-[2-(4- methox yphenyl)ethyl]-4-piperidin-1-io¿ammonium tetrachlorocuprate(II), (C(28)H(33)FN(4)O)[CuCl(4)], contains diprotonated cations of astemizole hydrogen bonded to three Cl atoms in two different CuCl(4)(2-) anions, with Cl.N distances in the range 3.166 (4)-3.203 (4) A. The geometry around copper is flattened tetrahedral with significantly different Cu-Cl distances which lie in the range 2.1968 (14)-2.2861 (12) A. The phenylethyl C atoms of the (4-methoxyphenyl)ethyl group are disordered indicating the presence of two conformers in the crystals.

Astemizole↗