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L Granasy

Publications and source records attributed to L Granasy.

3 recordsLinked to original sources

Analytical density functional theory of homogeneous vapor condensation

Starting from an exact gradient transcription of the perturbative density functional theory of homogeneous vapor condensation, we propose an analytical approximation that reproduces the density profile and free energy of critical fluctuations to high accuracy. For a broad variety of substances, including nonpolar, weakly polar, and metallic liquids, the method predicts nucleation rates that are orders of magnitude closer to experiment than those from the classical approach. The present treatment incorporates detailed molecular theory into macroscopic modeling.

Journal Article↗

Regular dendritic patterns induced by nonlocal time-periodic forcing

The dynamic response of dendritic solidification to spatially homogeneous time-periodic forcing has been studied. Phase-field calculations performed in two dimensions (2D) and experiments on thin (quasi-2D) liquid-crystal layers show that the frequency of dendritic side branching can be tuned by oscillatory pressure or heating. The sensitivity of this phenomenon to the relevant parameters, the frequency and amplitude of the modulation, the initial undercooling and the anisotropies of the interfacial free energy, and molecule attachment kinetics, has been explored. It has been demonstrated that in addition the side-branching mode synchronous with external forcing as emerging from the linear Wentzel-Kramers-Brillouin analysis, modes that oscillate with higher harmonic frequencies are also present with perceptible amplitudes.

Journal Article↗