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L Hadji

Publications and source records attributed to L Hadji.

13 recordsLinked to original sources

Axisymmetric shapes and forces resulting from the interaction of a particle with a solidifying interface.

A steady state model of the interaction of a foreign particle with a solidifying interface in a microgravity environment is presented in order to examine the phenomenon of particle engulfment. The model considers the interception of a spherical impurity particle by a deformable solid-liquid interface. Three forces are present whenever the particle is in near contact with the solid front, namely, the disjoining pressure force, the thermal force, and the hydrodynamic pressure force. These forces arise due to (i) the disjoining pressure gradients resulting from the deformation of the interface behind the particle, (ii) the interface distortion caused by the difference between the coefficients of thermal conductance of the particle and melt, and (iii) the hydrodynamic pressure resulting from the melt flow driven by the pressure gradients in the gap between the particle and the interface. The model accounts for the modification of the melt's freezing point by these pressure terms. The dependence of the interface morphology on the various physical and processing parameters is revealed. These include the rate of solidification, the thermal gradient, the gap width, and the coefficients of thermal conductivity of the particle and the melt. The gap profile is calculated and used in the evaluation of the three forces that characterize the interaction. The analysis shows that the outcome of the interaction, i.e., particle engulfment or rejection, depends primarily on the competition between the hydrodynamic and thermal forces.

Journal Article↗

Morphology of a solidifying interface near a spherical particle: disjoining pressure effects.

Numerical simulations were conducted to determine the morphology of a solid-liquid interface near an insoluble spherical particle. The model accounts for the undercoolings due to the front's curvature and to the nonretarded van der Waals interactions. Our numerical results show that, in the near-contact region, the interface profile develops a sharp peak whose curvature has a logarithmic singularity. This is in agreement with the asymptotic analysis of a previously published equation for the interface profile.

Journal Article↗

Thermal force induced by the presence of a particle near a solidifying interface.

The presence of a foreign particle in the melt, ahead of a solid-liquid interface, leads to the onset of interfacial deformations if the thermal conductivity of the particle, k(p), differs from that of the melt, k(l). In this paper, the influence of the thermal conductivity contrast on the interaction between the solidifying interface and the particle is quantified. We show that the interface distortion gives rise to a thermal force whose expression is given by F(th)=2piLGa3(1-alpha)/(2+alpha)T(m), where L is the latent heat of fusion per unit volume, T(m) is the melting point, a is the particle's radius, G the thermal gradient in the liquid phase and alpha=k(p)/k(l). The derivation makes use of the following assumptions: (i) the particle is small compared to the horizontal extent of the interface, (ii) the particle is placed in the near proximity of the deformable solid-liquid interface, and (iii) the interface is practically immobile in the calculation of the thermal field, i.e., V<<k(l)G/L, where V is the interface growth velocity. An order of magnitude analysis shows that the magnitude of the thermal force may be greater than that of the forces that are usually accounted for in studies of particle-interface interaction, namely, the drag force and the force due to the disjoining pressure. The inclusion of the thermal force in the overall force balance is found to modify the value of the growth rate at which equilibrium is attained. The analysis leads to the prediction that the growth rate at equilibrium is increased for particles with a low thermal conductivity and is decreased for particles with a high thermal conductivity. The derivation of the thermal force is preceded by a detailed analysis of the influence of the thermal conductance contrast on the interface profile.

Journal Article↗

Asymptotic analysis of particle engulfmemt.

An asymptotic analysis is conducted on the interaction between an insoluble spherical particle and an advancing solid-liquid interface when the particle is in the near-contact region (gap thickness is much smaller than the particle's radius). The analysis considers only thermal effects in a pure substance. The interface equilibrium temperature includes the undercooling effects due to the front curvature and to the long-range intermolecular forces in the thin melt film behind the particle. An expression for the crystal-particle gap thickness is derived and used to calculate the threshold value for the front velocity V(T) which separates pushing from engulfment.

Journal Article↗

Release of a slow-reacting substance from rabbit platelets.

Washed rabbit platelets stimulated with platelet-activating factor, thrombin, or arachidonic acid, released a slow-reacting substance (SRS), whereas platelets aggregated by adenosine diphosphate did not. Production of platelet-derived SRS was neither affected by indomethacin nor aspirin but was reduced by large doses of eicosatetraynoic acid, an inhibitor of the cyclo-oxygenase and lipoxygenase. L-cysteine enhanced markedly the release of SRS from platelets. This SRS activity, which was antagonized by FPL 55712 and inactivated by arylsulfatase, followed the same elution pattern on Amberlite, silicic acid, and reverse phase high-pressure liquid chromatography columns as that described for the SRS from other origins. SRS activity released from platelets preincubated with [14C]arachidonic acid exhibited the same retention time as radioactivity in reverse phase high-pressure liquid chromatography. The release of a SRS from platelets is consistent with their implication in the pathogenesis of asthma and other lung diseases.

5,8,11,14-Eicosatetraynoic Acid↗

Partial characterization of human histaminopectic factor.

Sera from normal human subjects are pooled and fractions are isolated by salt precipitation. The fraction responsible for agglutinating histamine bound latex particles is further purified by column chromatography. The histaminopectic activity can thus be traced to a single protein present in the IgG fraction of normal human serum. Its absence or the presence of an inhibitor in serum from allergic subjects is also sought as well as correlations between plasma concentrations of known immunoglobulins and specific histaminopectic activity. Some of its physical-chemical properties are explored. Evidence was also presented pointing to the possible presence of an inhibitor of the histaminopectic factor in human atopic serum.

Agglutinins↗