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L Kondic

Publications and source records attributed to L Kondic.

10 recordsLinked to original sources

Dynamic structure formation at the fronts of volatile liquid drops.

We report on instabilities during the spreading of volatile liquids, with emphasis on the novel instability observed when isopropyl alcohol is deposited on a monocrystalline Si wafer. This instability is characterized by emission of drops ahead of the expanding front, with each drop followed by smaller, satellite droplets, forming the structures which we nickname "octopi" due to their appearance. A less volatile liquid, or a substrate of larger heat conductivity, suppresses this instability. We formulate a theoretical model that reproduces the main features of the experiment.

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Spreading of a thin two-dimensional strip of fluid on a vertical plane: experiments and modeling.

We study the thin-film flow of a constant volume of silicon oil (polydymethilsiloxane) spreading down a vertical glass plate. The initial condition is generated from a horizontal fluid filament of typical diameter 0.4 mm. Two optical diagnostic methods are used: One based on an anamorphic system, and the other on the Schlieren method. The first one allows for a detailed characterization of the early stable stage of the spreading which is used to estimate the thickness of the precursor film needed to model the flow. The second one captures the bidimensional pattern of the transversal film instability. We use these techniques to determine the film thickness profiles, and the evolution of the moving contact line, including its shape and Fourier spectra. The numerical simulations of the stable stage of spreading are in good quantitative agreement with the experimental results. We develop a model based on linear stability theory that predicts the evolution of the modes present in the linear stage of the instability.

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Flow of thin films on patterned surfaces: controlling the instability.

We present fully nonlinear time-dependent simulations of the gravity-driven flow of thin wetting liquid films. The computations of the flow on a homogeneous substrate show that the contact line, becomes unstable and develops a finger-like or sawtooth structure [Phys. Rev. Lett. 86, 632 (2001)]. These computations are extended to patterned surfaces, where surface heterogeneities are introduced in a controllable manner. We discuss the conditions that need to be satisfied so that surface properties lead to predictable pattern formation and controllable wetting of the substrate. These conditions are sensitive to the presence of noise which is introduced by random perturbations of the contact line. We analyze this sensitivity and suggest how the effects of noise can be minimized. Applications of these results to technologically relevant flows are discussed.

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Granular friction, Coulomb failure, and the fluid-solid transition for horizontally shaken granular materials.

We present the results of an extensive series of experiments, molecular dynamics simulations, and models that address horizontal shaking of a layer of granular material. The goal of this work was to better understand the transition between the "fluid" and "solid" states of granular materials. In the experiments, the material-consisting of glass spheres, smooth and rough sand-was contained in a container of rectangular cross section, and subjected to horizontal shaking of the form x=A sin(omega(t)). The base of the container was porous, so that it was possible to reduce the effective weight of the sample by means of a vertical gas flow. The acceleration of the shaking could be precisely controlled by means of an accelerometer mounted onboard the shaker, plus feedback control and lockin detection. The relevant control parameter for this system was the dimensionless acceleration, Gamma=Aomega(2)/g, where g was the acceleration of gravity. As Gamma was varied, the layer underwent a backward bifurcation between a solidlike state that was stationary in the frame of the shaker and a fluidlike state that typically consisted of a sloshing layer of maximum depth H riding on top of a solid layer. That is, with increasing Gamma, the solid state made a transition to the fluid state at Gamma(cu) and once the system was in the fluid state, a decrease in Gamma left the system in the fluidized state until Gamma reached Gamma(cd)<Gamma(cu). In the fluidized state, the flow consisted of back and forth sloshing at the shaker frequency, plus a slower convective flow along the shaking direction and additionally in the horizontal direction transverse to the shaking direction. Molecular dynamics simulations show that the last of these flows is associated with shear and dilation at the vertical sidewalls. For Gamma<Gamma(cu) and in the solid state, there was a "gas" of free particles sliding on the surface of the material. These constituted much less than one layer's worth of particles in all cases. If these "sliders" were suppressed by placing a thin strip of plastic on the surface, the hysteresis was removed, and the transition to fluidization occurred at a slightly lower value than Gamma(cd) for the free surface case. The hysteresis was also suppressed if a vertical gas flow from the base was sufficient to support roughly 40% of the weight of the sample. Both the transition to the fluid state from the solid and the reverse transition from the fluid to the solid were characterized by similar divergent time scales. If Gamma was increased above Gamma(cu) by a fractional amount epsilon=(Gamma-Gamma(cu))/Gamma(cu), where epsilon was small, there was a characteristic time tau=Aepsilon(-beta) for the transition from solid to fluid to occur, where beta is 1.00+/-0.06. Similarly, if Gamma was decreased below Gamma(cd) in the fluidized state by an amount epsilon=(Gamma-Gamma(cd))/Gamma(cd), there was also a transient time tau=Bepsilon(-beta), where beta is again indistinguishable from 1.00. In addition, the amplitudes A and B are essentially identical. By placing a small "impurity" on top of the layer, consisting of a heavier particle, we found that the exponent beta varied as the impurity mass squared and changed by a factor of 3. A simple Coulomb friction model with friction coefficients mu(k)<mu(s) for the fluid and solid states predicts a reversible rather than hysteretic transition to the fluid state, similar to what we observe with the addition of the small overload from a plastic strip. In an improved model, we provide a relaxational mechanism that allows the friction coefficient to change continuously between the low and high values. This model produces the hysteresis seen in experiments.

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Contact line instabilities of thin liquid films.

We present results of fully nonlinear time-dependent simulations of a thin liquid film flowing down an inclined plane. Within the lubrication approximation, and assuming complete wetting, we find that varying the inclination angle considerably modifies the shape of the emerging patterns (fingers versus sawtooth). Our results strongly suggest that the shape of the patterns is not necessarily related to either partial or complete coverage of the substrate, a technologically important feature of the flow. We find quantitative agreement with reported experiments and suggest new ones.

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Global models for moving contact lines.

We consider thin film flows driven by surface tension and gravity. Within the framework of the lubrication approximation, we study the contact line motion using global models where either precursor film or slip are allowed. We show that completely wetting films can be simulated under both conditions without requiring direct tracking of the contact line interface. We perform a comparative study of standard and positivity preserving numerical methods for these problems in one space dimension, with the ultimate goal of choosing the best method applicable to two-dimensional problems. We find a considerable computational advantage of the precursor film model over the slipping models.

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Dependence of single-bubble sonoluminescence on ambient pressure

Kondic et al.'s theory makes several specific predictions on the dependence of single-bubble sonoluminescence (SBSL) on ambient pressure. We have carried out experiments to verify these predictions for air bubbles in a water-glycerine mixture at about 17.5 kHz. The results show an increase in SBSL with reduced ambient pressure down to a critical value below which SBSL is extinguished. The results are all in good agreement with Kondic et al.'s theory and are also compatible with the dissociation hypothesis of Lohse et al.

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Dynamics of spherical particles on a surface: collision-induced sliding and other effects.

We present a model for the motion of hard spherical particles on a two-dimensional surface. The model includes both the interaction between the particles via collisions and the interaction of the particles with the substrate. We analyze in detail the effects of sliding and rolling friction, which are usually overlooked. It is found that the properties of this particulate system are influenced significantly by the substrate-particle interactions. In particular, sliding of the particles relative to the substrate after a collision leads to considerable energy loss for common experimental conditions. The presented results provide a basis that can be used to realistically model the dynamical properties of the system, and provide further insight into density fluctuations and related phenomena of clustering and structure formation.

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