PubMed Health⌕ Search

Biomedical subjects

Lide Zhang

Publications and source records attributed to Lide Zhang.

At least 19 recordsLinked to original sources
PubMed2007

Manipulation of the morphology of semiconductor-based nanostructures from core-shell nanoparticles to nanocables: the case of CdSe/SiO(2).

The morphology of CdSe/SiO(2) was manipulated from core-shell-structured nanoparticles to nanocables by using a chemical vapor deposition (CVD) process. The growth of nanocables, with cores no more than 20 nm in diameter, is initiated by the formation of core-shell nanoparticles with SiO(2) as matrix and CdSe clusters dispersed inside. After the subsequent vaporization of the SiO(2) matrix, the follow-up CdSe vapor crystallizes with the remaining CdSe clusters as nuclei to form CdSe nanowires as the furnace was cooled to 1200 degrees C. During the controlled cooling of the furnace, the SiO vapor re-deposits to sheathe the nanowires. The thickness of the shell and the diameter of core were successfully controlled. The photoluminescence measurements show that the CdSe/SiO(2) nanocables have strong visible-light emission bands located at 590 and 688 nm, which are attributed to the defects induced by SiO(2) sheaths nanowires and the quantum confinement effect of the CdSe, respectively. The UV/Vis absorption spectra of the naked CdSe nanowires further validate the above-mentioned quantum confinement effect. The deterministic growth of these nanocables is very important for the design of the nanodevices based on them.

Journal Article↗
PubMed2006

High-density, aligned SiO2 nanowire arrays: microscopic imaging of the unique growth style and their ultraviolet light emission properties.

High-density, free-standing SiO2 nanowire arrays were successfully fabricated by a simple chemical vapor deposition method through a controlled pattern of the micrometer-sized alloyed balls on the Si substrate combined with a local balanced and steady-state reaction vapor environment. The direct observation of temporal evolution of the SiO2 nanowire growth process via the microscopic imaging approach offers us amazing pictures related to the unique vapor-liquid-solid (VLS) growth styles. These novel results are beneficial to understanding the formation mechanism of silica nanowire arrays, and at the same time, they extend our knowledge of VLS growth phenomena. The stable and strong ultraviolet emission properties of the as-grown products are of significant interest for their potential applications related to nanoscale optoelectronic device including ultraviolet-light-emitting devices, etc.

Journal Article↗
PubMed2006

SiO2 nanowires growing on hexagonally arranged circular patterns surrounded by TiO2 films.

An effective approach has been demonstrated for the synthesis of novel composite architectures, SiO2 nanowires (NWs) growing on hexagonally arranged circular patterns surrounded by TiO2 films on Si substrate. First, a solution-dipping template strategy is used to create TiO2 films with hexagonally arranged pores on Au-coated Si substrate, resulting in hexagonally arranged circular patterns of catalysts surrounded by TiO2 films. Then the patterned catalysts guide the growth of SiO2 NWs with the original TiO2 films preserved, realizing the composite structures. Such composite architectures combine the photoluminescence (PL) properties of the two components, and also present more favorable PL property, laying a foundation for future advanced nano-optoelectronic devices.

Membranes, Artificial↗
PubMed2006

Microarrays of silver nanowires embedded in anodic alumina membrane templates: size dependence of polarization characteristics.

Polarization characteristics of microarrays of silver nanowires embedded in an anodic alumina membrane are theoretically investigated. The microarrays mainly transmit the p-polarized wave, whereas they strongly attenuate the s-polarized wave in the near- and mid-infrared spectral range. We show that the sizes (e.g., diameter, spacing, and ratio of diameter to spacing) of the nanowires strongly affect the optical losses for the polarized waves. It is predicted that large extinction ratios and small insertion losses can be simultaneously achieved by an appropriate choice of the ratio and the diameter. An optimized design of a nanowire grid polarizer at near- and mid-infrared wavelengths is presented.

Journal Article↗
PubMed2006

Periodically twinned nanowires and polytypic nanobelts of ZnS: The role of mass diffusion in vapor-liquid-solid growth.

There are two mass diffusion processes regarding the vapor-liquid-solid (VLS) growth of nanostructures: one is inside the catalyst droplet toward the liquid-solid interface; the other is along the side surface planes of the growing nanostructures. In this letter, microscale, modulated mass diffusion scenarios are exhibited through the synthesis of two types of ZnS nanostructures in an Au-catalyzed VLS process: periodically twinned nanowires originated from periodical fluctuation between diffusion rate inside the catalytic droplet and the growth rate on the liquid-solid interface; the formation of asymmetrically polytypic nanobelts is related to one certain side surface bounded by high surface-energy plane, which serves as a preferential diffusion direction of reactant adatoms. The results may have important impact on the understanding of the physical and chemical process of the VLS mechanism. These longitudinally and latitudinally tunable crystalline structures enrich the family of one-dimensional nano-building blocks, and may find potential applications in nanotechnology.

Computer Simulation↗
PubMed2006

Large-scale synthesis of a novel tri(8-hydroxyquioline) aluminum nanostructure.

A novel tri(8-hydroxyquioline) aluminum (AlQ3) nanostructure was prepared on large scale at low cost by low-temperature physical vapor deposition (PVD). The morphologies, the chemical bondings, and photoluminescence of the AlQ3 nanostructure were investigated by environmental scanning electronic microscopy (ESEM), Fourier transform infrared spectrum (FT-IR), and photoluminescence (PL) spectra, respectively. The AlQ3 nanostructure was composed of micro-sphere with nanowire-cluster growing on the surface. The diameter of micro-sphere and nanowire were about 5 microm and 80 nm, respectively. FT-IR results indicated that the AlQ3 molecule had a strong thermal stability under research conditions. The growth mechanism of the novel nanostructure was discussed. The novel organic nanostructure would be believed to attractive building field-emission devices and other optical devices.

Aluminum↗
PubMed2005

Zinc oxide nanostructures: morphology derivation and evolution.

Zinc oxide nanostructures of various types, including nanobelts, nanoplatelets, nanowires, and nanorods, have been synthesized via well-developed routes by many research groups. However, so far, the underlying mechanism for the morphology derivation and evolution of the nanostructures has not been elucidated in depth. In this article, we report the systematic investigation of the morphology evolution characteristics of ZnO nanostructures from dense rods to dense nanoplatelets, nanoplatelet flowers, dense nanobelt flowers, and nanowire flowers in an evaporation-physical transport-condensation approach. Through the use of crystal growth theory, the determining factors for the formation of different nanostructural morphologies were found to be gas-phase supersaturation and the surface energy of the growing surface planes. Other experimental parameters such as the temperature at the source and the substrate, the temperature difference and the distance between the source and the substrate, the heating rate of the furnace, the gas flow rate, the ceramic tube diameter, and the starting material are all correlated with supersaturation and impose an effect on the morphology evolution. This finding may have an important impact on the qualitative understanding of the morphology evolution of nanostructures and the achieving of desired nanostructures controllably.

Journal Article↗
PubMed2005

Fabrication and characterization of single-crystalline ZnTe nanowire arrays.

Semiconductor ZnTe nanowire arrays have been synthesized by the pulsed electrochemical deposition from aqueous solutions into porous anodic alumina membranes. X-ray diffraction analyses show that the as-synthesized nanowires have a highly preferential orientation. Scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy indicate that high-filling, ordered, and single-crystalline nanowire arrays have been obtained. The optical absorption spectra of the nanowire arrays show that the optical absorption band edge of the ZnTe nanowire array exhibits a blue shift compared with that of bulk ZnTe. The growth mechanism and the electrochemical deposition process are discussed together with the chemical compositions analysis.

Journal Article↗
PubMed2005

Kinetics-driven growth of orthogonally branched single-crystalline magnesium oxide nanostructures.

Orthogonally branched single-crystalline magnesium oxide nanostructures were synthesized through a simple chemical vapor transport and condensation process in a flowing Ar/O(2) atmosphere. Other morphologies, such as cubes and nanowires, can also be obtained under different controlled conditions. The formation of different types of nanostructures can be tuned by modifying oxygen partial pressure during the synthesis. All the nanostructures are cubic single-crystalline enclosed by low-index {100} facets. Growth mechanisms for the nanostructures are discussed in detail: different supersaturation ratios, relatively high substrate temperatures, and surface defects in certain crystallographic planes cooperatively take important effects on determining the product morphologies. Structural defect-related blue light emission of the three types of MgO nanostructures was investigated. The MgO nanostructures with abundant morphologies may find applications in various nanodevices, and the kinetics-driven methodology might be exploited to synthesize similar nanostructures of other functional oxide materials.

Journal Article↗
PubMed2005

The formation of mesoporous TiO2 spheres via a facile chemical process.

The mesoporous TiO(2) solid and hollow spheres have been synthesized via a controllable and simple chemical route. Structural characterization indicates that these TiO(2) mesoporous spheres after calcined at 500 degrees C have an obvious mesoporous structure with the diameters of 200-300 nm for solid spheres and 200-500 nm for hollow spheres. The average pore sizes and BET surface areas of the mesoporous TiO(2) solid and hollow spheres are 6.8, 7.0 nm and 162, 90 m(2)/g, respectively. Optical adsorption investigation shows that TiO(2) solid and hollow spheres possess a direct band gap structure with the optical band gap of 3.68 and 3.75 eV, respectively. A possible formation mechanism for TiO(2) solid and hollow spheres is discussed.

Journal Article↗
PubMed2005

Comparison of short-term toxicity between Nano-Se and selenite in mice.

We previously reported that, as compared with selenite, nano red elemental selenium (Nano-Se) had lower acute toxicity in mice and similar bioavailability in terms of up-regulating seleno-enzymes. The short-term toxicity of both selenite and Nano-Se in mice was further compared in this study. At an oral dose of 6 mg/kg bw per day administered for consecutive 12 days, selenite and Nano-Se completely and partially suppressed mice growth respectively. Abnormal liver function was more pronounced with selenite treatment than Nano-Se as indicated by the increase of both alanine aminotransferase and aspartate aminotransferase in serum. Selenite inhibited liver catalase and superoxide dismutase activities, whereas, Nano-Se did not affect these two antioxidant enzymes. Selenite increased the malondialdehyde content of liver, but Nano-Se decreased it. Both Se forms had similar effects on depletion of reduced glutathione and up-regulated glutathione peroxidase. Nano-Se was more potent than selenite in the induction of glutathione S-transferase. At oral doses of 2 or 4 mg/kg bw per day for consecutive 15 days, selenite was more active than Nano-Se in supressing growth, deleting reduced glutathione, and inhibiting superoxide dismutase activities. Taken together, these results indicate that over a short-term, a high-dose of selenite caused more pronounced oxidative stress, greater liver injury, and prominent retardation of growth as compared to Nano-Se.

Alanine Transaminase↗
PubMed2005

Fabrication and optical property of silicon oxide layer coated semiconductor gallium nitride nanowires.

Quasi one-dimensional GaN-SiO(2) nanostructures, with a silicon oxide layer coated on semiconductor GaN nanowires, were successfully synthesized through as-synthesized SiO(2) nanoparticles-assisted reaction. The experimental results indicate that the nanostructure consists of single-crystalline wurtzite GaN nanowire core, an amorphous SiO(2) outer shell separated in the radial direction. These quasi one-dimensional nanowires have the diameters of a few tens of nanometers and lengths up to several hundreds of micrometers. The photoluminescence spectrum of the GaN-SiO(2) nanostructures consists of one broad blue-light emission peak at 480 nm and another weak UV emission peak at 345 nm. The novel method, which may results in high yield and high reproducibility, is demonstrated to be a unique technique for producing nanostructures with controlled morphology.

Gallium↗
PubMed2005

In-situ deposition of Pd nanoparticles on tubular halloysite template for initiation of metallization.

Halloysite template has a tubular microstructure; its wall has a multi-layer aluminosilicate structure. A new catalytic method is adopted here, through the in-situ reduction of Pd ions on the surface of tubular halloysite by methanol to initiate electroless plating; the detailed deposition features of Pd nanoparticles are investigated for the first time. The results indicate that an in-situ reduction and deposition of Pd occurs at room temperature, in which the halloysite template plays an important role. Impurities in halloysite (such as ferric oxide) influence the formation and distribution of the Pd nanoparticles. The Pd nanoparticles are of a non-spherical shape in most cases, which would be caused by the irregular appearance of halloysite. No intercalation of the nanoparticles occurs between the aluminosilicate layers in the halloysite. The diameter of Pd nanoparticles increases with time; the average diameter ranges from 1 nm to 4 nm. Pd nanoparticles on a halloysite template can catalyze electroless deposition of Ni to prepare a novel nano-sized cermet at low cost. This practicable catalytic method could also be used on other clay substrates for the initiation of metallization.

Aluminum Silicates↗
PubMed2005

Deposition feature of Ni nanoparticles on halloysite template and magnetic properties of the composite.

A novel cermet composite with Ni nanoparticles deposited on a hollow cylindrical halloysite template is fabricated by electroless plating. Ni nanoparticles have a uniform distribution on the template, and their average diameter is mainly in the range of 20-30 nm. The halloysite template will be beneficial to make the Ni nanoparticles achieve high stability and well-dispersed state. Different heat treatment temperatures have a great effect on the crystal structure of Ni nanoparticles and the magnetic properties of the composite. With the heat-treated temperature increase, Ni nanoparticles gradually become crystallized, and the composite values of inherent coercive force (iHc), saturated magnetization (Ms), and residual magnetization (Mr) increase respectively. After complete crystallization of Ni nanoparticles at 673 K, the composite has the maximum values of iHc (253.6 Oe), Ms (57.37 emu/g), and Mr (21.64 emu/g). The sum contribution of the magneto-crystalline anisotropy, single magnetic domain effect, and the pinning effect of multiple-twinned planar defects in Ni nanoparticles would result in the high value of iHc. The new nanosized cermet composite will be at such an advantage for its practicable fabrication method, higher coercive force, high stability, and low cost that it would have great potential to be utilized to design and prepare magnetic materials.

Aluminum Silicates↗
PubMed2004

Nano red elemental selenium has no size effect in the induction of seleno-enzymes in both cultured cells and mice.

We previous reported that a nano red elemental selenium (Nano-Se) in the range from 20 approximately 60 nm had similar bioavailability to sodium selenite (BioFactors 15 (2001) 27). We recently found that Nano-Se with different size had marked difference in scavenging an array of free radicals in vitro, the smaller the particle, the better scavenging activity (Free Radic. Biol. Med. 35 (2003) 805). In order to examine whether there is a size effect of Nano-Se in the induction of Se-dependent enzymes, a range of Nano-Se (5 approximately 200 nm) have been prepared based on the control of elemental Se atom aggregation. The sizes of Nano-Se particles were inversely correlated with protein levels in the redox system of selenite and glutathione. Different sizes of red elemental Se were prepared by adding varying amount of bovine serum albumin (BSA). Three different sizes of Nano-Se (5 approximately 15 nm, 20 approximately 60 nm, and 80 approximately 200 nm) have been chosen for the comparison of biological activity in terms of the induction of seleno-enzyme activities. Results showed that there was no significant size effect of Nano-Se from 5 to 200 nm in the induction of glutathione peroxidase (GPx), phospholipid hydroperoxide glutathione peroxidase (PHGPx) and thioredoxin reductase-1 (TrxR-1) in human hepatoma HepG2 cells and the livers of mice.

Animals↗
PubMed2004

Synthesis of Eu2O3 nanotube arrays through a facile sol-gel template approach.

Eu2O3 nanotubes have been successfully fabricated by an improved sol-gel template method within the nanochannels of porous anodic alumina templates. The morphology, structure, and composition of the nanotubes were characterized by means of X-ray diffraction techniques, scanning electron microscope, transmission electron microscopy, and selected-area electron diffraction. The results show that the Eu2O3 nanotubes are polycrystalline with a cubic structure. The outer diameter of nanotubes is 50-80 nm, and the thickness of the tube wall is about 5 nm. The mechanism of nanotube formation was discussed.

Journal Article↗
PubMed2003

CdSe-filled silica nanotubes.

The novel nanostructures, CdSe-filled silica nanotubes with diameter about 100 nm and length up to several micrometres, were synthesized through a simple thermochemistry method. CdSe nanorods inside the nanotubes are structurally uniform and single crystalline growing along the < 100 > direction.

Journal Article↗