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Biomedical subjects

M Bajić

Publications and source records attributed to M Bajić.

At least 19 recordsLinked to original sources

Benzdiamidine.

The molecule of benzene-1,4-dicarboxamidine or benzdiamidine, C(8)H(10)N(4), reveals C(i) symmetry. Hydrogen bonds utilize the amino groups as double donors, whereas the imino groups act as double acceptors. The network formed is similar to that observed in the crystal packing of terephthalamide.

Journal Article↗

Mass spectral fragmentation patterns of some new benzo[b]thiophene- and thieno[2,3-b]thiophene-2,5-dicarbonyldichlorides and -dicarbonyldianilides and anilidoquinolones.

The electron impact mass spectra of some benzo[b]thiophene- and thieno[2,3-b]thiophene-2,5-dicarbonyldichlorides, 2,5-dicarbonyldianalides, 9-anilido-benzo[b]thienyl[2,3-c]quinolones and 9-anilidothieno[4,5-b']thienyl[2,3-c]quinolones are discussed. Dominant peaks in dianilides are formed by cleavage of the C-N bond on one side of the anilido group, as well as on the anilido group itself in anilidoquinolones. These ions fragment further by the cleavage of a C-C bond in dianilides and the CONRPh group is lost directly, while the quinolonic part of the molecule in quinolones fragments with low probability. Characteristic fragment ions of dicarbonyldichlorides arise by the cleavage of the C-C1 bond.

Aniline Compounds↗

Mass spectral fragmentation patterns of some new 3,7-dichloro-benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid dianilides and 3,5-dichloro-dithieno[3,2-b:2',3'-d]thiophene-2,6-dicarboxylic acid dianilides. II.

The electron impact mass spectra of some benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid dianilides and dithieno[3,2-b:2',3'-d]thiophene-2,6-dicarboxylic acid dianilides are discussed. Dominant peaks in these dianilides are formed by the cleavage of a C-N bond on one side of an anilino group. These ions fragment further by the cleavage of a C-C bond on the other side of an anilino group and a CONRPhR' group may be lost directly. After loss of CO, the characteristic benzodithiophene radical cation, C10H2S2Cl2[symbol: see text], at m/z 256 and the dithienothiophene radical cation, C8S3Cl2[symbol: see text], at m/z 262 are formed from their respective precursor compounds.

Anilides↗

Mass spectral fragmentation patterns of some 2-methyl-3-furancarboxanilides and 2-methyl-3-furancarbothioanilides. II.

The electron impact mass spectra of some 2-methyl-3-furancarboxanilides and 2-methyl-3-furancarbothioanilides are discussed. Dominant peaks are formed by simple cleavage of a C-N bond in the anilides as well as in the thioanilides. Thioanilides show some additional fragmentation pathways recently reported which are not seen in the anilides. (T. Jagodzinski and M. Stobiecki, Org. Mass Spectrom., Vol. 25, p. 333 (1990)).

Anilides↗

Morphodynamic reactive response of the pineal gland of rats chronically exposed to stable strong magnetic field.

Mature male Wistar rats were affected by a strong magnetic field of 0.70 T for 20 min per day for 2 weeks. A short distance between the electromagnet pole expansions allowed interposition of one restrained animal only. The results obtained showed that the immobilization stress increased the peptidergic activity of both light and dark pinealocytes. In the animals exposed to the magnetic field, a dual morphodynamic response was observed: the peptidergic activity of light pinealocytes was obviously reduced versus the unimpaired stress-stimulated functional engagement of dark pinealocytes. The probability that the retina----pineal gland magnetoreceptor-magnetoeffector circuit is formed through the accentuation of the suppression of the noradrenaline input on light pinealocytes is discussed. It is also hypothesized that a potentially harmful bioeffect of a strong magnetic field could be manifested second to the impairment of the activity of light pinealocytes in organisms coping with stress.

Animals↗