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M Dolores Marcos

Publications and source records attributed to M Dolores Marcos.

9 recordsLinked to original sources
PubMed2006

Anchoring dyes into multidimensional large-pore zeolites: a prospective use as chromogenic sensing materials.

A versatile procedure for anchoring dyes into the pores of multidimensional zeolites by including organic dye precursors in the synthesis gel has been developed. To prove the concept, an aniline-functionalised zeolite Beta was obtained by reaction of triethylorthosilicate (TEOS), tetraethylammonium hydroxide, and N-methyl,N-(propyl-3-trimethoxysilyl)aniline (MPTMSA) in the presence of HF. Further extraction of the structure-directing agents resulted in a highly crystalline, white, functionalised zeolite Beta containing anchored aniline groups. Similar organic functionalised molecular sieves (OFMS) have been explored as novel catalysts, but, as far as we know, OFMS have never been used as precursors for dye-immobilisation or to design new solid-based host systems for selective molecular sensing processes as is reported here. In a second step the solids containing dyes were prepared by reaction of the hybrid material with the appropriate reactives to obtain tricyanovinylbenzene, triphenylpyrylium, azoic, and squaraine derivatives. All these reactions are straightforward and involve electrophilic aromatic substitution or diazotisation reactions at the electron-rich aniline ring. The final dye-functionalised solid materials were isolated by simple filtration and washing procedures and have been characterised by a number of techniques. In all cases the Beta structure of the solid remains unaltered. Among the large number of areas where dye-containing zeolites might be of importance, we were interested in testing their unconventional use as heterosupramolecular hosts in chromogenic protocols. To check their potential use as chemosensors, microporous solids with anchored triphenylpyrilium and squaraine dyes were selected and used as sensors for the chromogenic discrimination of amines. It was found that the response of both solids to amines was basically governed by the three-dimensional (3D) solid architecture that tuned the intrinsic unselective reactivity of the pyrylium dye. By using new solid-state supramolecular chemistry protocols we believe that these, and similar future dye-zeolite hosts, might be promising new sensor materials allowing the visible discrimination of selected target guests by size and/or polarity within families or closely related molecules.

Journal Article↗
PubMed2005

Rational design of a chromo- and fluorogenic hybrid chemosensor material for the detection of long-chain carboxylates.

A strategy for the rational design of a new optical sensor material for the selective recognition of long-chain carboxylates in water is presented. The approach relies on the combination of structure-property relationships to single out the optimal molecular sensor unit and the tuning of the sensing characteristics of an inorganic support material. A spacer-substituted 7-urea-phenoxazin-3-one was employed as the signaling moiety and a mesoporous trimethylsilylated UVM-7 (MCM-41 type) material served as the solid support. The sensor material shows the advantageous features of both modules that is absorption and emission in the visible spectral range, a fluorescence red-shift and enhancement upon analyte coordination, and the amplification of noncovalent (binding) and hydrogen-bonding (recognition) interactions in the detection event. Besides these basic results that are related to the design and performance of the sensor material, the paper discusses general aspects of amido-substituted phenoxazinone photophysics and addresses some general features of molecular anion recognition chemistry in aqueous vs nonaqueous media, utilizing steady-state and time-resolved optical as well as NMR spectroscopies. Detailed studies on potentially competing biochemical species and a first access to the schematic model of the response of the sensor material as obtained by a combination of fluorescence lifetime distribution analysis and Langmuir-type fitting of the gross binding constants complement the key issues of the paper.

Anions↗
PubMed2002

Silica-based powders and monoliths with bimodal pore systems.

Porous pure and doped silicas with pore sizes at two length scales (meso/macroporous) have been prepared and shaped both as powders and monoliths through a one-pot surfactant assisted procedure by using a simple template agent and starting from atrane complexes as inorganic precursors.

Journal Article↗